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On-surface photo-dissociation of C-Br bonds: towards room temperature Ullmann coupling.
Chem Commun (Camb) ; 51(63): 12593-6, 2015 Aug 14.
Artigo em Inglês | MEDLINE | ID: mdl-26154619
ABSTRACT
The surface-assisted synthesis of gold-organometallic hybrids on the Au(111) surface both by thermo- and light-initiated dehalogenation of bromo-substituted tetracene is reported. Combined X-ray photoemission (XPS) and scanning tunneling microscopy (STM) data reveal a significant increase of the surface order when mild reaction conditions are combined with 405 nm light irradiation.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Chem Commun (Camb) Assunto da revista: Química Ano de publicação: 2015 Tipo de documento: Artigo