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A family of 12-azametallacrown-4 structural motif with heterometallic Mn(III) -Ln-Mn(III) -Ln (Ln=Dy, Er, Yb, Tb, Y) alternate arrangement and single-molecule magnet behavior.
Chemistry ; 21(41): 14478-85, 2015 Oct 05.
Artigo em Inglês | MEDLINE | ID: mdl-26295925
ABSTRACT
Mixed 3d-4f 12-azametallacrown-4 complexes, [Mn2 Ln2 (OH)2 (hppt)4 (OAc)2 (DMF)2 ]⋅2 DMF⋅H2 O [Ln=Dy (1), Er (2), Yb (3), Tb (4) and Y (5), H2 hppt=3-(2-hydroxyphenyl)-5-(pyrazin-2-yl)-1,2,4-triazole)], were synthesized by reactions of H2 hppt with Mn(OAc)2 ⋅4 H2 O and Ln(NO3 )3 ⋅6 H2 O. This is the first 3d-4f azametallacrown family to incorporate Ln ions into the ring sets. These isostructural complexes exhibit alternating arrangements of two Mn and two Ln ions in the rings with each pair of metal centers bound by an NN group and µ2 -O bridging. Magnetic measurements revealed dominant antiferromagnetic interactions between metal centers, and frequency-dependent out-of-phase (${\chi {^\prime}{^\prime}_{\rm{M}} }$) signals below 4 K suggest slow relaxation of magnetization.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Chemistry Assunto da revista: Química Ano de publicação: 2015 Tipo de documento: Artigo