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Brightness and Color Tuning in a Series of Lanthanide-Based Coordination Polymers with Benzene-1,2,4,5-tetracarboxylic Acid as a Ligand.
Freslon, Stéphane; Luo, Yun; Daiguebonne, Carole; Calvez, Guillaume; Bernot, Kevin; Guillou, Olivier.
Afiliação
  • Freslon S; INSA, UMR 6226, Institut des Sciences Chimiques de Rennes , 20 Avenue des buttes de Coësmes, F-35708 Rennes, France.
  • Luo Y; INSA, UMR 6226, Institut des Sciences Chimiques de Rennes , 20 Avenue des buttes de Coësmes, F-35708 Rennes, France.
  • Daiguebonne C; INSA, UMR 6226, Institut des Sciences Chimiques de Rennes , 20 Avenue des buttes de Coësmes, F-35708 Rennes, France.
  • Calvez G; INSA, UMR 6226, Institut des Sciences Chimiques de Rennes , 20 Avenue des buttes de Coësmes, F-35708 Rennes, France.
  • Bernot K; INSA, UMR 6226, Institut des Sciences Chimiques de Rennes , 20 Avenue des buttes de Coësmes, F-35708 Rennes, France.
  • Guillou O; INSA, UMR 6226, Institut des Sciences Chimiques de Rennes , 20 Avenue des buttes de Coësmes, F-35708 Rennes, France.
Inorg Chem ; 55(2): 794-802, 2016 Jan 19.
Artigo em Inglês | MEDLINE | ID: mdl-26714204
ABSTRACT
Reactions in water between the sodium salt of benzene-1,2,4,5-tetracarboxylic acid (H4btec) and lanthanide ions (Sm-Dy) led to a series of isostructural lanthanide-based coordination polymers with the general chemical formula [Ln4(btec)3(H2O)12·20H2O]∞ with Ln = Sm-Dy. The family has been structurally characterized. From a luminescent point of view, the heterodinuclear strategy has been successfully applied and allows significant brightness enhancement (+35%) and color tuning from green to yellow to orange to red.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Inorg Chem Ano de publicação: 2016 Tipo de documento: Artigo País de afiliação: França