Your browser doesn't support javascript.
para-Selective Alkylation of Benzamides and Aromatic Ketones by Cooperative Nickel/Aluminum Catalysis.
J Am Chem Soc ; 138(44): 14699-14704, 2016 11 09.
Artigo em Inglês | MEDLINE | ID: mdl-27759372
ABSTRACT
We report a method that ensures the selective alkylation of benzamides and aromatic ketones at the para-position via cooperative nickel/aluminum catalysis. Using a bulky catalyst/cocatalyst system allows reactions between benzamides and alkenes to afford the corresponding para-alkylated products. The origin of the high para-selectivity has also been investigated by density functional theory calculations.

Similares

MEDLINE

...
LILACS

LIS

Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: J Am Chem Soc Ano de publicação: 2016 Tipo de documento: Artigo País de afiliação: Japão