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A decacobalt(ii) cluster with triple-sandwich structure obtained by partial reductive hydrolysis of a pentacobalt(ii/iii) Weakley-type polyoxometalate.
Chem Commun (Camb) ; 52(90): 13245-13248, 2016 Nov 03.
Artigo em Inglês | MEDLINE | ID: mdl-27774535
ABSTRACT
Partial reductive hydrolysis of a penta-CoII/III cluster [Co(H2O)2(CoIIIW9O34)(PW9O34)]12- (1) leads to the formation of [Co2{Co3(H2O)(Co(OH)2W7O26)(PW9O34)}2]22- (2). This polyoxometalate is made up of two capping [PW9O34]9- units and two bridging [W7O26]10- units that assemble to encapsulate a novel deca-CoII cluster core comprising octahedral and tetrahedral CoII ions.

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Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Chem Commun (Camb) Assunto da revista: Química Ano de publicação: 2016 Tipo de documento: Artigo