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The EPR Spectrum of Triplet Mesitylphosphinidene: Reassignment and New Assignment.
Angew Chem Int Ed Engl ; 56(27): 7944-7947, 2017 06 26.
Artigo em Inglês | MEDLINE | ID: mdl-28493313
ABSTRACT
Low-temperature UV-photolysis of mesitylphosphiranes under highly anaerobic conditions leads to the formation of the triplet mesitylphosphinidene (MesP). The recorded X-band EPR spectrum of triplet MesP and the derived zero-field splitting parameter D=4.116 cm-1 differ significantly from those reported previously for this intermediate. New magnetic parameters of mesitylphosphinidene are discussed along with the results of DFT calculations.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Angew Chem Int Ed Engl Ano de publicação: 2017 Tipo de documento: Artigo País de afiliação: Federação Russa