Your browser doesn't support javascript.
loading
Synthesis of new hybrid 1,4-thiazinyl-1,2,3-dithiazolyl radicals via Smiles rearrangement.
Vasko, Petra; Hurmalainen, Juha; Mansikkamäki, Akseli; Peuronen, Anssi; Mailman, Aaron; Tuononen, Heikki M.
Afiliação
  • Vasko P; Department of Chemistry, NanoScience Centre, P.O. Box 35, FI-40014 University of Jyväskylä, Finland. aaron.m.mailman@jyu.fi heikki.m.tuononen@jyu.fi.
Dalton Trans ; 46(46): 16004-16008, 2017 Nov 28.
Artigo em Inglês | MEDLINE | ID: mdl-29116268
ABSTRACT
The condensation reaction of 2-aminobenzenethiols and 3-aminopyrazinethiols with 2-amino-6-fluoro-N-methylpyridinium triflate afforded thioether derivatives that were found to undergo Smiles rearrangement and cyclocondensation with sulphur monochloride to yield new hybrid 1,4-thiazine-1,2,3-dithiazolylium cations. The synthesized cations were readily reduced to the corresponding stable neutral radicals with spin densities delocalized over both 1,4-thiazinyl and 1,2,3-dithiazolyl moieties.

Similares

MEDLINE

...
LILACS

LIS

Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Dalton Trans Assunto da revista: Química Ano de publicação: 2017 Tipo de documento: Artigo