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Hexalanthanide Complexes as Molecular Precursors: Synthesis, Crystal Structure, and Luminescent and Magnetic Properties.
Yao, Haiyun; Calvez, Guillaume; Daiguebonne, Carole; Bernot, Kevin; Suffren, Yan; Puget, Marin; Lescop, Christophe; Guillou, Olivier.
Afiliação
  • Yao H; INSA Rennes , UMR CNRS 6226 "Institut des Sciences Chimiques de Rennes", 20 Avenue des buttes de Coesmes, F-35708 Rennes, France.
  • Calvez G; INSA Rennes , UMR CNRS 6226 "Institut des Sciences Chimiques de Rennes", 20 Avenue des buttes de Coesmes, F-35708 Rennes, France.
  • Daiguebonne C; INSA Rennes , UMR CNRS 6226 "Institut des Sciences Chimiques de Rennes", 20 Avenue des buttes de Coesmes, F-35708 Rennes, France.
  • Bernot K; INSA Rennes , UMR CNRS 6226 "Institut des Sciences Chimiques de Rennes", 20 Avenue des buttes de Coesmes, F-35708 Rennes, France.
  • Suffren Y; INSA Rennes , UMR CNRS 6226 "Institut des Sciences Chimiques de Rennes", 20 Avenue des buttes de Coesmes, F-35708 Rennes, France.
  • Puget M; INSA Rennes , UMR CNRS 6226 "Institut des Sciences Chimiques de Rennes", 20 Avenue des buttes de Coesmes, F-35708 Rennes, France.
  • Lescop C; INSA Rennes , UMR CNRS 6226 "Institut des Sciences Chimiques de Rennes", 20 Avenue des buttes de Coesmes, F-35708 Rennes, France.
  • Guillou O; INSA Rennes , UMR CNRS 6226 "Institut des Sciences Chimiques de Rennes", 20 Avenue des buttes de Coesmes, F-35708 Rennes, France.
Inorg Chem ; 56(23): 14632-14642, 2017 Dec 04.
Artigo em Inglês | MEDLINE | ID: mdl-29125752
ABSTRACT
Reaction of hexanuclear octahedral molecular precursors with a 3-chlorobenzoate ligand affords an unprecedented family of isostructural polylanthanide complexes via solvothermal and microwave-assisted syntheses in an acetonitrile medium. The general chemical formula of the compounds that constitute this series is {[Ln6(µ3-OH)2(H2O)2(NO3)2(3-cb)14]·(CH3CN)4}, where 3-cb- stands for 3-chlorobenzoate and Ln = Eu, Tb, Dy, Ho, Er, or Y. The crystal structure, solubility, and magnetic and luminescent properties of these complexes have been studied. The luminescent properties evidence that the composition of the hexalanthanide precursor is preserved during the synthetic process that is of particular interest for cases in which heterolanthanide complexes are targeted.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Inorg Chem Ano de publicação: 2017 Tipo de documento: Artigo País de afiliação: França