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A long-range ordered array of copper tetrameric units embedded in an on-surface metal organic framework.
J Chem Phys ; 147(21): 214706, 2017 Dec 07.
Artigo em Inglês | MEDLINE | ID: mdl-29221400
ABSTRACT
We report on the assembly of a highly ordered array of copper tetrameric clusters, coordinated into a metal-organic network. The ordered cluster array has been achieved by the deposition of tetrahydroxyquinone molecules on the Cu(111) surface at room temperature, and subsequent thermally activated dehydrogenation with the formation of tetraoxyquinone tetra-anions with a 4 × 4 periodicity. The supramolecular organic network acts as a spacer for the highly ordered two-dimensional network of copper tetramers at the very surface.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: J Chem Phys Ano de publicação: 2017 Tipo de documento: Artigo País de afiliação: Itália