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Two Consecutive Magneto-Structural Gas-Solid Transformations in Non-Porous Molecular Materials.
Chemistry ; 24(47): 12426-12432, 2018 Aug 22.
Artigo em Inglês | MEDLINE | ID: mdl-29989253
ABSTRACT
Modification of the magnetic properties in a solid-state material upon external stimulus has attracted much attention in the recent years for their potential applications as switches and sensors. Within the field of coordination polymers, gas sorption studies typically focus on porous solids, with the gas molecules accommodating in the channels. Here we present a 1D non-porous coordination polymer capable of incorporating HCl gas molecules, which not only causes a reordering of its atoms in the solid state but also provokes dramatic changes in the magnetic behavior. Subsequently, a further solid-gas transformation can occur with the extrusion of HCl gas molecules causing a second structural rearrangement, which is also accompanied by modification in the magnetic path between the metal centers. Unequivocal evidence of the two-step magnetostructural transformation is provided by X-ray single-crystal diffraction.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Chemistry Assunto da revista: Química Ano de publicação: 2018 Tipo de documento: Artigo País de afiliação: Espanha