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Synthesis, characterization and third-order nonlinear optical properties of a dodecaruthenium organometallic dendrimer with a zinc(ii) tetraphenylporphyrin core.
Merhi, Areej; Grelaud, Guillaume; Morshedi, Mahbod; Abid, Seyfallah; Green, Katy A; Barlow, Adam; Groizard, Thomas; Kahlal, Samia; Halet, Jean-François; Ngo, Hoang Minh; Ledoux, Isabelle; Cifuentes, Marie P; Humphrey, Mark G; Paul, Frédéric; Paul-Roth, Christine O.
Afiliação
  • Merhi A; Univ Rennes, INSA Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) - UMR 6226, F-35000 Rennes, France. frederic.paul@univ-rennes1.fr.
Dalton Trans ; 47(32): 11123-11135, 2018 Aug 14.
Artigo em Inglês | MEDLINE | ID: mdl-30043792
ABSTRACT
A new Zn(ii) porphyrin-based dendrimer (52) containing twelve Ru(ii) alkynyl fragments, has been prepared following a convergent approach in two steps from 5,10,15,20-tetra(4-ethynylphenyl)porphyrinatozinc(ii) (6). The cubic nonlinear optical (NLO) properties of 52 and other derivatives of 6 have been measured by third-harmonic generation (THG) at 1907 nm and by Z-scan over the spectral range 500-1700 nm, revealing the remarkable NLO response of 52 in the near-IR range. These results highlight the beneficial role of the extended "cross fourchée"-like polymetallic structure of 52 on its third-order NLO properties.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Dalton Trans Assunto da revista: Química Ano de publicação: 2018 Tipo de documento: Artigo País de afiliação: França