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A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO2.
Duyar, Melis S; Tsai, Charlie; Snider, Jonathan L; Singh, Joseph A; Gallo, Alessandro; Yoo, Jong Suk; Medford, Andrew J; Abild-Pedersen, Frank; Studt, Felix; Kibsgaard, Jakob; Bent, Stacey F; Nørskov, Jens K; Jaramillo, Thomas F.
Afiliação
  • Duyar MS; SUNCAT Center for Interface Science and Catalysis, Stanford University, Stanford, CA, 94305, USA.
  • Tsai C; SLAC National Accelerator Laboratory, Menlo Park, CA, 94025, USA.
  • Snider JL; SUNCAT Center for Interface Science and Catalysis, Stanford University, Stanford, CA, 94305, USA.
  • Singh JA; SLAC National Accelerator Laboratory, Menlo Park, CA, 94025, USA.
  • Gallo A; SUNCAT Center for Interface Science and Catalysis, Stanford University, Stanford, CA, 94305, USA.
  • Yoo JS; SLAC National Accelerator Laboratory, Menlo Park, CA, 94025, USA.
  • Medford AJ; SUNCAT Center for Interface Science and Catalysis, Stanford University, Stanford, CA, 94305, USA.
  • Abild-Pedersen F; SLAC National Accelerator Laboratory, Menlo Park, CA, 94025, USA.
  • Studt F; SUNCAT Center for Interface Science and Catalysis, Stanford University, Stanford, CA, 94305, USA.
  • Kibsgaard J; SLAC National Accelerator Laboratory, Menlo Park, CA, 94025, USA.
  • Bent SF; SUNCAT Center for Interface Science and Catalysis, Stanford University, Stanford, CA, 94305, USA.
  • Nørskov JK; SLAC National Accelerator Laboratory, Menlo Park, CA, 94025, USA.
  • Jaramillo TF; SUNCAT Center for Interface Science and Catalysis, Stanford University, Stanford, CA, 94305, USA.
Angew Chem Int Ed Engl ; 57(46): 15045-15050, 2018 Nov 12.
Artigo em Inglês | MEDLINE | ID: mdl-30134041
ABSTRACT
Methanol is a major fuel and chemical feedstock currently produced from syngas, a CO/CO2 /H2 mixture. Herein we identify formate binding strength as a key parameter limiting the activity and stability of known catalysts for methanol synthesis in the presence of CO2 . We present a molybdenum phosphide catalyst for CO and CO2 reduction to methanol, which through a weaker interaction with formate, can improve the activity and stability of methanol synthesis catalysts in a wide range of CO/CO2 /H2 feeds.
Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Angew Chem Int Ed Engl Ano de publicação: 2018 Tipo de documento: Artigo País de afiliação: Estados Unidos

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Angew Chem Int Ed Engl Ano de publicação: 2018 Tipo de documento: Artigo País de afiliação: Estados Unidos
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