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Lanthanide-Based Coordination Polymers With 1,4-Carboxyphenylboronic Ligand: Multiemissive Compounds for Multisensitive Luminescent Thermometric Probes.
Abdallah, Ahmad; Freslon, Stéphane; Fan, Xiao; Rojo, Amandine; Daiguebonne, Carole; Suffren, Yan; Bernot, Kevin; Calvez, Guillaume; Roisnel, Thierry; Guillou, Olivier.
Afiliação
  • Abdallah A; Univ Rennes, INSA Rennes, CNRS, UMR 6226 "Institut des Sciences Chimiques de Rennes" , F-35000 Rennes , France.
  • Freslon S; Univ Rennes, INSA Rennes, CNRS, UMR 6226 "Institut des Sciences Chimiques de Rennes" , F-35000 Rennes , France.
  • Fan X; Univ Rennes, INSA Rennes, CNRS, UMR 6226 "Institut des Sciences Chimiques de Rennes" , F-35000 Rennes , France.
  • Rojo A; Univ Rennes, INSA Rennes, CNRS, UMR 6226 "Institut des Sciences Chimiques de Rennes" , F-35000 Rennes , France.
  • Daiguebonne C; Univ Rennes, INSA Rennes, CNRS, UMR 6226 "Institut des Sciences Chimiques de Rennes" , F-35000 Rennes , France.
  • Suffren Y; Univ Rennes, INSA Rennes, CNRS, UMR 6226 "Institut des Sciences Chimiques de Rennes" , F-35000 Rennes , France.
  • Bernot K; Univ Rennes, INSA Rennes, CNRS, UMR 6226 "Institut des Sciences Chimiques de Rennes" , F-35000 Rennes , France.
  • Calvez G; Univ Rennes, INSA Rennes, CNRS, UMR 6226 "Institut des Sciences Chimiques de Rennes" , F-35000 Rennes , France.
  • Roisnel T; Univ Rennes, INSA Rennes, CNRS, UMR 6226 "Institut des Sciences Chimiques de Rennes" , F-35000 Rennes , France.
  • Guillou O; Univ Rennes, INSA Rennes, CNRS, UMR 6226 "Institut des Sciences Chimiques de Rennes" , F-35000 Rennes , France.
Inorg Chem ; 58(1): 462-475, 2019 Jan 07.
Artigo em Inglês | MEDLINE | ID: mdl-30540189
ABSTRACT
Reactions in water of lanthanide chlorides with the sodium salt of 1,4-carboxyphenylboronic acid lead to two series of isostructural compounds with respective general chemical formulas [Ln(cpb)3(H2O)2]∞ for Ln = La or Ce and [Ln(cpbOH)(H2O)2·(cpb)]∞ for Ln = Pr-Lu (except Pm) plus Y. Heterolanthanide coordination polymers that are isostructural to the second series have been synthesized, and their photophysical properties have been studied. This study evidences that it is possible to design multiemissive lanthanide-based coordination polymers that could find their application as multigauge luminescent thermometric probes.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Inorg Chem Ano de publicação: 2019 Tipo de documento: Artigo País de afiliação: França