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Supramolecular aggregation of a redox-active copper-naphthalenediimide network with intrinsic electron conduction.
Chem Commun (Camb) ; 55(11): 1643-1646, 2019 Jan 31.
Artigo em Inglês | MEDLINE | ID: mdl-30657485
ABSTRACT
A sextuple ordered interpenetrated copper-naphthalenediimide network has been constructed by combining the features of porous metal-organic frameworks and π-conjugated supramolecular aggregation. The material exhibits intrinsic semiconductive features with narrow bandgap energy (1.2 eV) and outstanding electron transport. Theoretical calculations combined with experiments indicate that the high electron conduction may originate from π-d coupling and J-aggregation.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Chem Commun (Camb) Assunto da revista: Química Ano de publicação: 2019 Tipo de documento: Artigo