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Synthesis and crystal structure of a new coordination polymer based on lanthanum and 1,4-phenyl-enedi-acetate ligands.
Camara, Magatte; Badiane, Insa; Diallo, Mamoudou; Daiguebonne, Carole; Guillou, Olivier.
Afiliação
  • Camara M; Université Assane Seck de Ziguinchor, LCPM-Groupe Matériaux Inorganiques Chimie Douce et Cristallographie, BP 523 Ziguinchor, Senegal.
  • Badiane I; Université Assane Seck de Ziguinchor, LCPM-Groupe Matériaux Inorganiques Chimie Douce et Cristallographie, BP 523 Ziguinchor, Senegal.
  • Diallo M; Université Assane Seck de Ziguinchor, LCPM-Groupe Matériaux Inorganiques Chimie Douce et Cristallographie, BP 523 Ziguinchor, Senegal.
  • Daiguebonne C; Université de Rennes, INSA Rennes, CNRS UMR 6226, Institut des Sciences Chimiques de Rennes, F-35708 Rennes, France.
  • Guillou O; Université de Rennes, INSA Rennes, CNRS UMR 6226, Institut des Sciences Chimiques de Rennes, F-35708 Rennes, France.
Acta Crystallogr E Crystallogr Commun ; 75(Pt 3): 378-382, 2019 Mar 01.
Artigo em Inglês | MEDLINE | ID: mdl-30867953
ABSTRACT
Reaction in gel between the sodium salt of 1,4-phenyl-enedi-acetic acid (Na2C10O4H8-Na2 p-pda) and lanthanum chloride yields single crystals of the three-dimensional coordination polymer poly[[tetra-aqua-tris-(µ-1,4-phenyl-enedi-acetato)-dilanthanum(III)] octa-hydrate], {[La2(C10H8O4)3(H2O)4]·8H2O}∞. The LaIII coordination polyhedron can be described as a slightly distorted monocapped square anti-prism. One of the two p-pda2- ligands is bound to four LaIII ions and the other to two LaIII ions. Each LaIII atom is coordinated by five ligands, thereby generating a metal-organic framework with potential porosity properties.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Acta Crystallogr E Crystallogr Commun Ano de publicação: 2019 Tipo de documento: Artigo País de afiliação: Senegal