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Reversible Oxygen Redox Chemistry in Aqueous Zinc-Ion Batteries.
Wan, Fang; Zhang, Yan; Zhang, Linlin; Liu, Daobin; Wang, Changda; Song, Li; Niu, Zhiqiang; Chen, Jun.
Afiliação
  • Wan F; Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center, College of Chemistry, Nankai University, Tianjin, 300071, P. R. China.
  • Zhang Y; Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center, College of Chemistry, Nankai University, Tianjin, 300071, P. R. China.
  • Zhang L; Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center, College of Chemistry, Nankai University, Tianjin, 300071, P. R. China.
  • Liu D; National Synchrotron Radiation Laboratory, School of Chemistry and Materials Science, CAS Center for Excellence in Nanoscience, University of Science and Technology of China, Hefei, 230026, P. R. China.
  • Wang C; National Synchrotron Radiation Laboratory, School of Chemistry and Materials Science, CAS Center for Excellence in Nanoscience, University of Science and Technology of China, Hefei, 230026, P. R. China.
  • Song L; National Synchrotron Radiation Laboratory, School of Chemistry and Materials Science, CAS Center for Excellence in Nanoscience, University of Science and Technology of China, Hefei, 230026, P. R. China.
  • Niu Z; Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center, College of Chemistry, Nankai University, Tianjin, 300071, P. R. China.
  • Chen J; Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center, College of Chemistry, Nankai University, Tianjin, 300071, P. R. China.
Angew Chem Int Ed Engl ; 58(21): 7062-7067, 2019 May 20.
Artigo em Inglês | MEDLINE | ID: mdl-30893503
ABSTRACT
Rechargeable aqueous zinc-ion batteries (ZIBs) are promising energy-storage devices owing to their low cost and high safety. However, their energy-storage mechanisms are complex and not well established. Recent energy-storage mechanisms of ZIBs usually depend on cationic redox processes. Anionic redox processes have not been observed owing to the limitations of cathodes and electrolytes. Herein, we describe highly reversible aqueous ZIBs based on layered VOPO4 cathodes and a water-in-salt electrolyte. Such batteries display reversible oxygen redox chemistry in a high-voltage region. The oxygen redox process not only provides about 27 % additional capacity, but also increases the average operating voltage to around 1.56 V, thus increasing the energy density by approximately 36 %. Furthermore, the oxygen redox process promotes the reversible crystal-structure evolution of VOPO4 during charge/discharge processes, thus resulting in enhanced rate capability and cycling performance.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Angew Chem Int Ed Engl Ano de publicação: 2019 Tipo de documento: Artigo