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A Rutile TiO2 Electron Transport Layer for the Enhancement of Charge Collection for Efficient Perovskite Solar Cells.
Angew Chem Int Ed Engl ; 58(28): 9414-9418, 2019 Jul 08.
Artigo em Inglês | MEDLINE | ID: mdl-31041835
Interfacial charge collection efficiency has demonstrated significant effects on the power conversion efficiency (PCE) of perovskite solar cells (PSCs). Herein, crystalline phase-dependent charge collection is investigated by using rutile and anatase TiO2 electron transport layer (ETL) to fabricate PSCs. The results show that rutile TiO2 ETL enhances the extraction and transportation of electrons to FTO and reduces the recombination, thanks to its better conductivity and improved interface with the CH3 NH3 PbI3 (MAPbI3 ) layer. Moreover, this may be also attributed to the fact that rutile TiO2 has better match with perovskite grains, and less trap density. As a result, comparing with anatase TiO2 ETL, MAPbI3 PSCs with rutile TiO2 ETL delivers significantly enhanced performance with a champion PCE of 20.9 % and a large open circuit voltage (VOC ) of 1.17 V.





Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Angew Chem Int Ed Engl Ano de publicação: 2019 Tipo de documento: Artigo País de afiliação: China