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On-Surface Photochemistry of Pre-Ordered 1-Methyl-2-phenyl-acetylenes: C-H Bond Activation and Intermolecular Coupling on Highly Oriented Pyrolytic Graphite.
Chemphyschem ; 20(18): 2317-2321, 2019 09 17.
Artigo em Inglês | MEDLINE | ID: mdl-31245897
ABSTRACT
In this contribution we report on light-induced metal-free coupling of propynylbenzene molecular units on highly oriented pyrolytic graphite. The reaction occurs within the self-assembled monolayer and leads to the generation of covalently coupled 1,5-hexadiyne and para-terphenyl derivatives under topological control. Such photochemical uncatalysed pathway represents an original approach in the field of topological C-C coupling at the solid/liquid interface and provides new insight into the low temperature formation of aromatic compounds at the surface of carbonaceous supports.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Chemphyschem Assunto da revista: Biofísica / Química Ano de publicação: 2019 Tipo de documento: Artigo