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Development of PVDF Ultrafiltration Membrane with Zwitterionic Block Copolymer Micelles as a Selective Layer.
Membranes (Basel) ; 9(8)2019 Aug 01.
Artigo em Inglês | MEDLINE | ID: mdl-31374830
In recent years, block copolymer micellar assemblies with the formation of structured nanoparticles have been considered as an emerging technology in membrane science. In this work, the poly(methyl methacrylate)-block-poly(sulfobetaine methacrylate) copolymer was directly synthesized using Reversible Addition-Fragmentation chain Transfer (RAFT) polymerization and self-assembled in a selective medium (2,2,2-trifluroethanol/water). Then, poly(methyl methacrylate)-block-poly(sulfobetaine methacrylate) copolymers were casted onto a commercial PVDF membrane to form a thin porous selective layer. The prepared nanoparticles and the resulting membranes were fully characterized using microscopy methods (SEM and AFM), whereas the membrane performance was evaluated in terms of permeability and the molecular weight cut off. The results from this study demonstrate the preparation of an ultrafiltration membrane made from the assembly of poly(methyl methacrylate)-block-poly(sulfobetaine methacrylate) copolymer micelles on the top of a PVDF membrane in the form of thin film. The copolymer chain orientation leads to a membrane surface enriched in hydrophilic PSBMA, which confers a suitable behavior for aqueous solution filtration on the membrane, while preserving the high chemical and mechanical resistance of the PVDF.





Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Ano de publicação: 2019 Tipo de documento: Artigo País de afiliação: França