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Two microporous CoII-MOFs with dual active sites for highly selective adsorption of CO2/CH4 and CO2/N2.
Dalton Trans ; 48(36): 13541-13545, 2019 Sep 17.
Artigo em Inglês | MEDLINE | ID: mdl-31469147
ABSTRACT
Simultaneously involving abundant [NH2(CH3)2]+ cations and uncoordinated carboxylate oxygen atoms as dual active sites, two microporous CoII-MOFs (LCU-105 and LCU-106, LCU = Liaocheng University) both exhibit highly selective adsorption of CO2/CH4 and CO2/N2. GCMC theoretical simulations provide good verification of the experimental results.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Dalton Trans Assunto da revista: Química Ano de publicação: 2019 Tipo de documento: Artigo