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Nitrogen-thermal modification of the bifunctional interfaces of transition metal/carbon dyads for the reversible hydrogenation and dehydrogenation of heteroarenes.
Chem Commun (Camb) ; 55(76): 11394-11397, 2019 Sep 19.
Artigo em Inglês | MEDLINE | ID: mdl-31482882
ABSTRACT
A nitrogen-thermal approach via the reaction between transition metal species and N dopants affords us the ability to optimize the tradeoff between the number of exposed transition metal/carbon (exemplified by cobalt in this work) boundaries and the most pronounced interfacial rectifying contact to achieve the highly efficient and selective hydrogenation and dehydrogenation of N-heterocycle compounds in a reversible manner.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Chem Commun (Camb) Assunto da revista: Química Ano de publicação: 2019 Tipo de documento: Artigo