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Morphology control of metal-modified zirconium phosphate support structures for the oxygen evolution reaction.
Ramos-Garcés, Mario V; Sanchez, Joel; La Luz-Rivera, Kálery; Del Toro-Pedrosa, Daniel E; Jaramillo, Thomas F; Colón, Jorge L.
Afiliação
  • Ramos-Garcés MV; Department of Chemistry, University of Puerto Rico at Río Piedras, 17 Ave. Universidad STE 1701, San Juan, PR 00925-2537, USA. jorge.colon10@upr.edu and PREM Center for Interfacial Electrochemistry of Energy Materials, University of Puerto Rico, San Juan, PR 00925, USA.
  • Sanchez J; Department of Chemical Engineering, Stanford University, Stanford, CA 94305, USA and SUNCAT Center for Interface Science and Catalysis, Stanford University, CA 94305, USA.
  • La Luz-Rivera K; Department of Chemistry, University of Puerto Rico at Río Piedras, 17 Ave. Universidad STE 1701, San Juan, PR 00925-2537, USA. jorge.colon10@upr.edu and PREM Center for Interfacial Electrochemistry of Energy Materials, University of Puerto Rico, San Juan, PR 00925, USA.
  • Del Toro-Pedrosa DE; Department of Chemistry, University of Puerto Rico at Río Piedras, 17 Ave. Universidad STE 1701, San Juan, PR 00925-2537, USA. jorge.colon10@upr.edu.
  • Jaramillo TF; Department of Chemical Engineering, Stanford University, Stanford, CA 94305, USA and SUNCAT Center for Interface Science and Catalysis, Stanford University, CA 94305, USA.
  • Colón JL; Department of Chemistry, University of Puerto Rico at Río Piedras, 17 Ave. Universidad STE 1701, San Juan, PR 00925-2537, USA. jorge.colon10@upr.edu and PREM Center for Interfacial Electrochemistry of Energy Materials, University of Puerto Rico, San Juan, PR 00925, USA.
Dalton Trans ; 49(12): 3892-3900, 2020 Mar 24.
Artigo em Inglês | MEDLINE | ID: mdl-31894216
ABSTRACT
The electrochemical oxygen evolution reaction (OER) is the half-cell reaction for many clean-energy production technologies, including water electrolyzers and metal-air batteries. However, its sluggish kinetics hinders the performance of those technologies, impeding them from broader implementation. Recently, we reported the use of zirconium phosphate (ZrP) as a support for transition metal catalysts for the oxygen evolution reaction (OER). These catalysts achieve promising overpotentials with high mass activities. Herein, we synthesize ZrP structures with controlled morphology hexagonal platelets, rods, cubes, and spheres, and subsequently modify them with Co(ii) and Ni(ii) cations to assess their electrochemcial OER behavior. Through inductively coupled plasma mass-spectrometry measurements, the maximum ion exchange capacity is found to vary based on the morphology of the ZrP structure and cation selection. Trends in geometric current density and mass activity as a function of cation selection are discussed. We find that the loading and coverage of cobalt and nickel species on the ZrP supports are key factors that control OER performance.
Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Dalton Trans Assunto da revista: Química Ano de publicação: 2020 Tipo de documento: Artigo País de afiliação: Estados Unidos

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Dalton Trans Assunto da revista: Química Ano de publicação: 2020 Tipo de documento: Artigo País de afiliação: Estados Unidos
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