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Emission Control by Molecular Manipulation of Double-Paddled Binuclear PtII Complexes at the Air-Water Interface.
Chem Asian J ; 15(3): 406-414, 2020 Feb 03.
Artigo em Inglês | MEDLINE | ID: mdl-31922659
ABSTRACT
Molecular functions depend on conformations and motions of the corresponding molecular species. An air-water interface is a suitable asymmetric field for the control of molecular conformations and motions under a small applied force. In this work, double-paddled binuclear PtII complexes containing pyrazole rings linked by alkyl spacers were synthesized and their orientations and emission properties dynamically manipulated at the air-water interface. The complexes emerge from water with concurrent variation of interface orientation of the planes of the PtII complexes from perpendicular to parallel during mechanical compression suggesting a unique 'submarine emission'. Phosphorescence of the complexes is quenched at the air-water interface prior to monolayer formation with intensities subsequently rapidly increasing during monolayer compression. These results indicate that asymmetric reactions and motions might be controlled by applying mechanical force at the air-water interface.

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Texto completo: Disponível Coleções: Bases de dados internacionais Base de dados: MEDLINE Idioma: Inglês Revista: Chem Asian J Ano de publicação: 2020 Tipo de documento: Artigo País de afiliação: Japão