A high dimensional oxysulfide built from large iron-based clusters with partial charge-ordering.

Almoussawi, Batoul; Arevalo-Lopez, Angel M; Simon, Pardis; Kabbour, Houria

Almoussawi, Batoul; Arevalo-Lopez, Angel M; Simon, Pardis; Kabbour, Houria.

Afiliação

Almoussawi B; Univ. Lille, CNRS, Centrale Lille, ENSCL, Univ. Artois, UMR 8181 - UCCS - Unité de Catalyse et Chimie du Solide, Lille F-59000, France. houria.kabbour@univ-lille.fr.
Arevalo-Lopez AM; Univ. Lille, CNRS, Centrale Lille, ENSCL, Univ. Artois, UMR 8181 - UCCS - Unité de Catalyse et Chimie du Solide, Lille F-59000, France. houria.kabbour@univ-lille.fr.
Simon P; Univ. Lille, CNRS, Centrale Lille, ENSCL, Univ. Artois, UMR 8181 - UCCS - Unité de Catalyse et Chimie du Solide, Lille F-59000, France. houria.kabbour@univ-lille.fr.
Kabbour H; Univ. Lille, CNRS, Centrale Lille, ENSCL, Univ. Artois, UMR 8181 - UCCS - Unité de Catalyse et Chimie du Solide, Lille F-59000, France. houria.kabbour@univ-lille.fr.

Chem Commun (Camb) ; 57(89): 11859-11862, 2021 Nov 09.

Article em En | MEDLINE | ID: mdl-34704560

ABSTRACT

ABSTRACT

Herein we report the original Ba10Fe7.75Zn5.25S18Si3O12 oxysulfide which crystallizes in a new structural type. Contrary to the usual oxychalcogenides, it crystallizes with a non-centrosymmetric 3D spatial network structure built from large magnetic clusters consisting of twelve (Fe2+/3+/Zn)S3O tetrahedra decorating a central Fe2+S6 octahedron and exhibiting a spin glass state.

Texto completo

Adicionar na Minha BVS

Imprimir

XML

PubMed Links

Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2021 Tipo de documento: Article País de afiliação: França País de publicação: ENGLAND / ESCOCIA / GB / GREAT BRITAIN / INGLATERRA / REINO UNIDO / SCOTLAND / UK / UNITED KINGDOM

Texto completo

Adicionar na Minha BVS

Imprimir

XML

PubMed Links

Buscar no Google