Oriented 2D Perovskite Wafers for Anisotropic X-ray Detection through a Fast Tableting Strategy.
Adv Mater
; 34(8): e2108020, 2022 Feb.
Article
em En
| MEDLINE
| ID: mdl-34865244
ABSTRACT
2D perovskite single crystals have emerged as excellent optoelectronic materials owing to their unique anisotropic properties. However, growing large 2D perovskite single crystals remains challenging and time-consuming. Here, a new composition of lead-free 2D perovskite-4-fluorophenethylammonium bismuth iodide [(F-PEA)3 BiI6 ] is reported. An oriented bulk 2D wafer with a large area of 1.33 cm2 is obtained by tableting disordered 2D perovskite powders, resulting in anisotropic resistivities of 5 × 1010 and 2 × 1011 Ω cm in the lateral and vertical directions, respectively. Trivalent Bi3+ ions are employed to achieve a stronger ionic bonding energy with I- ions, which intrinsically suppress the ion-migration effect. Thus, the oriented wafer presents good capabilities in both charge collection and ion-migration suppression under a large applied bias along the out-of-plane direction, making it suitable for low-dosage X-ray detection. The large-area wafer shows a sensitive response to hard X-rays operated at a tube voltage of 120 kVp with the lowest detectable dose rate of 30 nGy s-1 . Thus, the fast tableting process is a facile and effective strategy to synthesize large-area, oriented 2D wafers, showing excellent X-ray detection performance and operational stability that are comparable to those of 2D perovskite single crystals.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Tipo de estudo:
Diagnostic_studies
Idioma:
En
Revista:
Adv Mater
Assunto da revista:
BIOFISICA
/
QUIMICA
Ano de publicação:
2022
Tipo de documento:
Article
País de publicação:
ALEMANHA
/
ALEMANIA
/
DE
/
DEUSTCHLAND
/
GERMANY