RESUMO
Photocatalytic disinfection practices have been applied for decades and attract current interest along with the developments in synthesis of novel photocatalysts. A survey based investigation was performed for elucidation of photocatalytic treatment details as well as disinfection mechanism of microorganisms. The present work brings significant information on the utilization of second generation TiO2 photocatalysts for inactivation of microorganisms typically using E. coli as the model microorganism. Special interest was devoted to the role of organic matrix either generated during treatment or as a natural component. Studies on photocatalytic disinfection were extensively reviewed and evaluated with respect to basic operational parameters related to photocatalysis, and types and properties of microorganisms investigated. Degradation mechanism and behavior of microorganisms towards reactive oxygen species during disinfection and organic matrix effects were also addressed. For successful utilization and effective assessment of visible light active photocatalysts, standard protocols for disinfection activity testing have to be set. Further improvement of the efficiency of these materials would be promising for future applications in water treatment processes.
Assuntos
Titânio/química , CatáliseRESUMO
Solar photocatalytic disinfection efficiency of novel visible light activated (VLA) photocatalysts was evaluated with the aim of assessing inactivation of Escherichia coli as the pathogen indicator organism present in drinking water. Influence of humic acid (HA) on the photocatalytic disinfection efficiency of the specified VLA TiO2 specimens i.e., N-doped, Se-doped, and Se-N co-doped TiO2 was also investigated. Photocatalytic disinfection efficiency was assessed by the enumeration of bacteria following selected irradiation periods. Degradation and compositional changes in organic matter (OM) was also tracked by means of UV-vis and advanced fluorescence spectroscopic (EEM features) parameters. Photocatalytic mineralization of the organic matter was followed by dissolved organic carbon contents. Presence of HA as a model organic compound of natural organic matter (NOM) displayed a retardation effect on solar photocatalytic abatement of E. coli. However, no distinctly different effect was observed under solar photolytic conditions due to the presence of HA. Regrowth of E. coli could not be assessed under the specified experimental conditions. A comparison was introduced with respect to the use of undoped TiO2 P-25 as the photocatalyst.