Efficient Removal of Tetracycline and Bisphenol A from Water with a New Hybrid Clay/TiO2 Composite.

New TiO2 hybrid composites were prepared from kaolin clay, predried and carbonized biomass, and titanium tetraisopropoxide and explored for tetracycline (TET) and bisphenol A (BPA) removal from water. Overall, the removal rate is 84% for TET and 51% for BPA. The maximum adsorption capacities (qm) are 30 and 23 mg/g for TET and BPA, respectively. These capacities are far greater than those obtained for unmodified TiO2. Increasing the ionic strength of the solution does not change the adsorption capacity of the adsorbent. pH changes only slightly change BPA adsorption, while a pH > 7 significantly reduces the adsorption of TET on the material. The Brouers-Sotolongo fractal model best describes the kinetic data for both TET and BPA adsorption, predicting that the adsorption process occurs via a complex mechanism involving various forces of attraction. Temkin and Freundlich isotherms, which best fit the equilibrium adsorption data for TET and BPA, respectively, suggest that adsorption sites are heterogeneous in nature. Overall, the composite materials are much more effective for TET removal from aqueous solution than for BPA. This phenomenon is assigned to a difference in the TET/adsorbent interactions vs the BPA/adsorbent interactions: the decisive factor appears to be favorable electrostatic interactions for TET yielding a more effective TET removal.

Carbon Adsorbents from Spent Coffee for Removal of Methylene Blue and Methyl Orange from Water.

Activated carbons (ACs) were prepared from dried spent coffee (SCD), a biological waste product, to produce adsorbents for methylene blue (MB) and methyl orange (MO) from aqueous solution. Pre-pyrolysis activation of SCD was achieved via treatment of the SCD with aqueous sodium hydroxide solutions at 90 °C. Pyrolysis of the pretreated SCD at 500 °C for 1 h produced powders with typical characteristics of AC suitable and effective for dye adsorption. As an alternative to the rather harsh base treatment, calcium carbonate powder, a very common and abundant resource, was also studied as an activator. Mixtures of SCD and CaCO3 (1:1 w/w) yielded effective ACs for MO and MB removal upon pyrolysis needing only small amounts of AC to clear the solutions. A selectivity of the adsorption process toward anionic (MO) or cationic (MB) dyes was not observed.