Phosphorus speciation in the marine sediment of Kalpakkam coast, southeast coast of India.

A study was carried out at Kalpakkam coast to find out the distribution of various fractions of phosphorus (P) in the marine sediment during pre-northeast monsoon period. Samples were collected from ten locations covering ~80 km(2) of the inner-shelf region. Sedimentary parameters such as sand, silt, clay, and organic carbon percentage were analyzed in order to find out their relation with various P fractions. The sediment was found to be predominantly sandy in nature with low silt and clay content. Among all the fractions (loosely bound (LoP), calcium bound (CaP), iron bound (FeP), aluminum bound (AlP), and organic (OP)), CaP fraction constituted the largest portion (68.7%) followed by organic fraction (16.3%). The bioavailable P fractions ranged from 5 to 44% of the total P (TP) content. Relatively high LoP content was observed at the offshore locations with comparatively high mud percentage as compared with the near-shore locations. As FeP and AlP concentrations were directly proportional to the amount of fine-grain sediment, the low levels of these fractions found in this coastal area were therefore attributed to the sandy nature of the sediments. The order of abundance of the major forms of P in the surface sediments of Kalpakkam coast was as follows: CaP > OP > LoP > AlP > FeP.

Formation and speciation characteristics of brominated trihalomethanes in seawater chlorination.

Formation character of brominated-trihalomethanes (Br-THMs) in chlorinated seawater and its dependence on applied chlorine dose, reaction time, and temperature were investigated in the laboratory. Seawater was collected from the east coast of India and a chlorine dose of 1, 3, 5, and 10 ppm was each applied at a temperature of 20, 30, and 40 degrees C to investigate the yield and kinetics of Br-THMs formation. Qualitative and quantitative estimation of THM formation at various intervals of time ranging from 5 min to 168 h was determined by a gas chromatograph equipped with an electron capture detector (GC-ECD). Chlorine dose, chlorine contact time, and reaction temperature positively affected the load of THMs. The ratio of chlorine dose to halogen incorporation decreased from 12% to 5% with increasing applied chlorine dose from 1 to 10 ppm. Significant levels of THMs were found to be formed within 0.5 h of reaction, followed by a very slow rate of formation. Elevated temperature favored both increased rate of formation and overall THM yield. The formation order of different trihalomethane species at all studied temperatures was observed to be bromodichloromethane (CHCl2Br) < dibromochloromethane (CHClBr2) < bromoform (CHBr3). Formation of chloroform was not observed, and bromoform was the dominant (96% to 98%) among the three THM species formed.

BASELINE EVALUATION STUDY OF NATURALLY OCCURRING RADIONUCLIDES IN SOIL SAMPLES FROM VICINITY OF INDIA'S FIRST FAST REACTOR FUEL CYCLE FACILITY (FRFCF), DAE COMPLEX, KALPAKKAM, INDIA.

The activity concentration of 238U, 232Th and 40K were measured in the soil samples collected from Fast Reactor Fuel Cycle Facility (FRFCF) site, using high-resolution gamma-ray spectrometry. This study is aimed to establish the baseline data of naturally occurring radionuclides within the site. The average activity concentrations were found to be 416.5, 61.7 and 622.3 Bq kg-1 for 40K, 238U and 232Th, respectively. The activity concentrations and its radiological indices were evaluated and were compared with the international values reported by the United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR). The ratio of 40K/232Th and 40K /238U were calculated, which indicates the presence of 5.79 and 2.69 times more K-bearing minerals as compared with Th and U-bearing minerals in the soil samples, respectively. The study provides baseline information on concentration of radionuclides and background radiological assessment of the FRFCF site.