Infrared phase measuring deflectometry by using defocused binary fringe.

Three-dimensional surface information acquisition of specular objects plays an important role in the fields of automobile industry, aerospace, cultural relic protection, intelligent robotics, equipment manufacturing, and so on. Most of the existing specular surface measurement methods are based on focused sinusoidal fringe patterns, so there are certain requirements for the range of the depth of field (DOF) of the camera on the focus position. However, for many specular surfaces with a large gradient, the tested objects may not always be in the DOF of the camera, so sinusoidal fringe patterns are defocused to be vulnerable to the noise. In this Letter, a new infrared phase measuring deflectometry (PMD) based on defocused binary fringe is proposed that combines a binary fringe defocusing technique and direct PMD. The measurement principle and the corresponding system calibration method are described. The feasibility and measurement accuracy of fringe defocus in specular measurement are studied in principle. The experimental results on several specular objects show that the proposed method can effectively measure specular surfaces out of the DOF of the camera.

Measurement of the Three-Dimensional Shape of Discontinuous Specular Objects Using Infrared Phase-Measuring Deflectometry.

Phase-measuring deflectometry (PMD)-based methods have been widely used in the measurement of the three-dimensional (3D) shape of specular objects, and the existing PMD methods utilize visible light. However, specular surfaces are sensitive to ambient light. As a result, the reconstructed 3D shape is affected by the external environment in actual measurements. To overcome this problem, an infrared PMD (IR-PMD) method is proposed to measure specular objects by directly establishing the relationship between absolute phase and depth data for the first time. Moreover, the proposed method can measure discontinuous surfaces. In addition, a new geometric calibration method is proposed by combining fringe projection and fringe reflection. The proposed IR-PMD method uses a projector to project IR sinusoidal fringe patterns onto a ground glass, which can be regarded as an IR digital screen. The IR fringe patterns are reflected by the measured specular surfaces, and the deformed fringe patterns are captured by an IR camera. A multiple-step phase-shifting algorithm and the optimum three-fringe number selection method are applied to the deformed fringe patterns to obtain wrapped and unwrapped phase data, respectively. Then, 3D shape data can be directly calculated by the unwrapped phase data on the screen located in two positions. The results here presented validate the effectiveness and accuracy of the proposed method. It can be used to measure specular components in the application fields of advanced manufacturing, automobile industry, and aerospace industry.

Three-Dimensional Shape Measurements of Specular Objects Using Phase-Measuring Deflectometry.

The fast development in the fields of integrated circuits, photovoltaics, the automobile industry, advanced manufacturing, and astronomy have led to the importance and necessity of quickly and accurately obtaining three-dimensional (3D) shape data of specular surfaces for quality control and function evaluation. Owing to the advantages of a large dynamic range, non-contact operation, full-field and fast acquisition, high accuracy, and automatic data processing, phase-measuring deflectometry (PMD, also called fringe reflection profilometry) has been widely studied and applied in many fields. Phase information coded in the reflected fringe patterns relates to the local slope and height of the measured specular objects. The 3D shape is obtained by integrating the local gradient data or directly calculating the depth data from the phase information. We present a review of the relevant techniques regarding classical PMD. The improved PMD technique is then used to measure specular objects having discontinuous and/or isolated surfaces. Some influential factors on the measured results are presented. The challenges and future research directions are discussed to further advance PMD techniques. Finally, the application fields of PMD are briefly introduced.

Self-assembly formation of Co quantum dot loaded N-doped porous carbon cathode for quinoline degradation in the electro-Fenton system.

Quinoline is high toxicity and difficult biodegradation in oil washing wastewater. Therefore, efficient removal of quinoline contaminant from water bodies poses a major challenge. Hence, Co quantum dot loaded N-doped porous carbon (CoNC) nanosheets grown in situ on carbon cloth were fabricated as cathode for the degradation of quinoline in electro-Fenton system. Under optimal conditions (c(Fe2+) = 0.5 mM, U = -0.3 V, pH = 3), quinoline was completely degraded within 15 min with superior apparent rate constant of 0.385 min-1, which was 19.6 times higher than that of the ZIF-L precursor, due to the abundance of Co QDs active sites and hydrophilicity and electrical conductivity of N-doped porous carbon. In addition, three reaction pathways for quinoline were deduced by combining Density Functional Theory (DFT) calculation and Liquid Chromatography-Mass Spectrometry (LC-MS). More importantly, in situ FTIR and free energy calculations were analyzed to reveal that pathway Ⅰ as spontaneous reaction was the main reaction pathway. Finally, the toxicity of the intermediates was assessed with ECOSAR software and E. coli experiments, and the overall toxicity decreased during the degradation reactions. This work provides novel perspectives on environmental protection by designing in-situ grown cathodes through self-assembly method, thereby effectively purifying pollutants from wastewater.