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1.
Nanotechnology ; 23(23): 235601, 2012 Jun 15.
Artigo em Inglês | MEDLINE | ID: mdl-22595866

RESUMO

Reduced graphene oxide nanoribbon fibers were fabricated by using an electrophoretic self-assembly method without the use of any polymer or surfactant. We report electrical and field emission properties of the fibers as a function of reduction degree. In particular, the thermally annealed fiber showed superior field emission performance with a low potential for field emission (0.7 V µm(-1)) and a giant field emission current density (400 A cm(-2)). Moreover, the fiber maintains a high current level of 300 A cm(-2) corresponding to 1 mA during long-term operation.


Assuntos
Cristalização/métodos , Grafite/química , Nanoestruturas/química , Nanoestruturas/ultraestrutura , Óxidos/química , Condutividade Elétrica , Substâncias Macromoleculares/química , Teste de Materiais , Conformação Molecular , Tamanho da Partícula , Propriedades de Superfície
2.
ACS Appl Mater Interfaces ; 8(28): 18513-8, 2016 Jul 20.
Artigo em Inglês | MEDLINE | ID: mdl-27302334

RESUMO

In this work, graphene field effect transistors (FETs) were fabricated on a trench structure made by carbonized poly(methylmethacrylate) to modify the graphene surface. The trench-structured devices showed different characteristics depending on the channel orientation and the pitch size of the trenches as well as channel area in the FETs. Periodic corrugations and barriers of suspended graphene on the trench structure were measured by atomic force microscopy and electrostatic force microscopy. Regular barriers of 160 mV were observed for the trench structure with graphene. To confirm the transfer mechanism in the FETs depending on the channel orientation, the ratio of experimental mobility (3.6-3.74) was extracted from the current-voltage characteristics using equivalent circuit simulation. It is shown that the number of barriers increases as the pitch size decreases because the number of corrugations increases from different trench pitches. The noise for the 140 nm pitch trench is 1 order of magnitude higher than that for the 200 nm pitch trench.

3.
ACS Appl Mater Interfaces ; 4(5): 2338-42, 2012 May.
Artigo em Inglês | MEDLINE | ID: mdl-22534584

RESUMO

A strategy for enhancing the heating performance of freestanding carbon nanotube (CNT) sheet is presented that involves decorating the sheet with granular-type palladium (Pd) particles. When Pd is added to the sheet, the heating efficiency of CNT sheet is increased by a factor of 3.6 (99.9 °C cm(2)/W vs 27.3 °C cm(2)/W with no Pd). Suppression of convective heat transfer loss attributes to the enhanced heat generation efficiency. However, higher heating response of CNT/Pd sheet was observed compared to CNT sheet, hence suggesting that the electron-lattice energy exchange could be additional heating mechanism in the presence of granular-type particles of Pd having a diameter of 10 nm or less. CNT sheet/Pd is quite stable, retaining its initial characteristics even after 300 cycles of on-off voltage pulses and shows fast thermal responses of the heating and cooling rates being 154 and -248 °C/s, respectively.

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