Quantifying relations and similarities of the meteorological parameters among the weather stations in the Alberta Oil Sands region.

Our objective was to quantify the similarity in the meteorological measurements of 17 stations under three weather networks in the Alberta oil sands region. The networks were for climate monitoring under the water quantity program (WQP) and air program, including Meteorological Towers (MT) and Edge Sites (ES). The meteorological parameters were air temperature (AT), relative humidity (RH), solar radiation (SR), barometric pressure (BP), precipitation (PR), and snow depth (SD). Among the various measures implemented for finding correlations in this study, we found that the use of Pearson's coefficient (r) and absolute average error (AAE) would be sufficient. Also, we applied the percent similarity method upon considering at least 75% of the value in finding the similarity between station pairs. Our results showed that we could optimize the networks by selecting the least number of stations (for each network) to describe the measure-variability in meteorological parameters. We identified that five stations are sufficient for the measurement of AT, one for RH, five for SR, three for BP, seven for PR, and two for SD in the WQP network. For the MT network, six for AT, two for RH, six for SR, and four for PR, and the ES network requires six for AT, three for RH, six for SR, and two for BP. This study could potentially be critical to rationalize/optimize weather networks in the study area.

Degradation of pharmaceutical mixtures in aqueous solutions using UV/peracetic acid process: Kinetics, degradation pathways and comparison with UV/H2O2.

This paper presents an evaluation of UV/PAA process for degradation of four pharmaceuticals venlafaxine (VEN), sulfamethoxazole (SFX), fluoxetine (FLU) and carbamazepine (CBZ) with comparison to UV/H2O2 process. The effectiveness of combining PAA and H2O2 at various proportions while irradiating with UVC were also evaluated. UVC/PAA (λ = 254 nm) was effective in degrading all four pharmaceuticals and followed pseudo first-order kinetics. Increasing PAA dosage or UVC intensity resulted in a linear increase in pseudo-first order rate coefficient. Both PAA in dark conditions and UVA/PAA (λ = 360 nm) were marginally effective to degrade SFX and ineffective to degrade VEN, CBZ and FLU; indicating the need for UVC irradiation for activation of PAA. For similar oxidant dosages of 50 mg/L UVC/H2O2 was found to be faster than UV/PAA for VEN, CBZ and FLU by 55%, 75% and 33%, respectively. Under similar conditions, SFX was degraded 24% faster by UV/PAA. Increase in the proportion of H2O2 to PAA in UVC/PAA/H2O2 improved kinetics of degradation compared to PAA alone. Tests on TOC were conducted to determine the amount of acetic acid that is released to water when treatment by UVC/PAA is conducted. Results demonstrated that 70% of PAA by mass was ultimately converted to acetic acid and remained in the treated solutions. Hydroxyl radical attack is hypothesized to be the main mechanism of degradation by UV/PAA as degradation intermediates identified for all the target pharmaceuticals coincided with by-products identified during UV/H2O2 process.

Pilot-scale investigation on nutrient removal characteristics of mineral-rich aerobic granular sludge: Identification of uncommon mechanisms.

This study investigated nutrient removal characteristics and the related pathways in aerobic granular reactors using three pilot-scale granular sequencing batch reactors (GSBRs) treating wastewaters of diverse carbon and nutrient strength. The GSBRs were operated with alternating (AN/O/AX/O_SBR and AN/O_SBR) and purely-aerobic (O_SBR) operation modes. Mineral-rich aerobic granules with hydroxyapatite (HAp) core were cultivated in all the three GSBRs. The highest nitrogen removal efficiency (75%) was achieved in AN/O/AX/O_SBR and O_SBR and the lowest (22%) in AN/O_SBR, establishing a quasi-linear relationship with organic loading rate (OLR). Phosphorus removal efficiencies of 55-63% were achieved in the GSBRs despite different influent PO4-P concentrations. Heterotrophic nitrification and biologically-induced phosphate precipitation (BIPP) became the dominant nutrient depletion pathways, contributing 61-84% and 39-96% to overall ammonium nitrogen and phosphorus removal, respectively. A direct relation was noted between heterotrophic nitrification efficiency (ηHeterotrophic nitrification) and nutrient availability, as nitrification efficiencies of 18 and 64% were observed for COD:Ninf of 5 and 20, respectively. Whereas, BIPP efficiency (ηBIPP) established inverse relation with (COD:P)inf and (Ca:P)inf and direct relation with phosphorus concentration beyond microbial growth requirement. Core heterotrophic nitrifiers and bio-calcifying species were identified as {Thauera and Flavobacterium} and {Flavobacterium, Acinetobacter, Pseudomonas, and Corynebacterium}, respectively. Ca-P crystallization was proposed to be via phosphate precipitation on calcite surfaces. Granulation mechanism was proposed as crystallization on bio-aggregates' periphery and then crystal growth toward the core.

Effect of UV dose on degradation of venlafaxine using UV/H2O2: perspective of augmenting UV units in wastewater treatment.

Many water and wastewater treatment plants (WWTPs) are fitted with a UV system that provides post treatment disinfection before the water is released to receiving water. This paper presents a study on expected removal for the pharmaceutical venlafaxine (VEN) in a typical UV unit at a municipal WWTP with analysis of removal rates of an advanced oxidation process using UV irradiation with injection of H2O2. The study is supported by bench scale degradation experiments on VEN. Results demonstrated that UV can completely degrade VEN, but the addition of H2O2 increased pseudo first order rate constant by up to 2.5 times. Extrapolations of the lab data indicated that removal rates of VEN at the UV disinfection unit of a typical municipal WWTP are approximately 0.4% at standard operating conditions. With the addition of 10 mg/L of H2O2, degradation of VEN can be increased by ten times over existing UV treatment. By studying the impact of adjusting parameters such as UV intensity, UV dosage, and H2O2 dosage, a framework is set to allow researchers and engineers to move forward with developing UV/H2O2 systems that meet their future design needs for pharmaceutical removal.

Augmentation of Biogranules for Enhanced Performance of Full-Scale Lagoon-Based Municipal Wastewater Treatment Plants.

This study investigated the treatment performance of lagoon-based municipal wastewater treatment plants (LWWTPs) inoculated by proprietary biogranules. Augmentation process included enhancing the microbial community of lagoon basins by weekly addition of biogranules over the treatment seasons (summer and fall). Effluent qualities before and after the augmentation process were compared, and the results were reported as "enhanced treatment efficiencies, EE". Very low concentrations of 5-day biochemical oxygen demand (BOD5), total nitrogen (TN), total Kjeldahl nitrogen (TKN), ammonium nitrogen (N-NH4), and total phosphorus (TP) were detected at discharge points after the augmentation process, which corresponded to enhanced treatment efficiencies of 86, 74, 72, 92.7, and 71%, respectively. Significant reduction in total coliform and E. coli concentrations in the effluents (91 and 98%, respectively) demonstrated the capability of granule-based lagoons in destroying pathogens. Adding biogranules to lagoons was an efficient remedy for excess sludge buildup in short and long runs. Hence, inoculating lagoon plants using biogranules was suggested as an effective technique to augment rural wastewater treatment facilities.

Denitrification performance and microbial versatility in response to different selection pressures.

This study investigated functional dynamics of microbial community in response to different selection pressures, with a focus on denitrification. Suspended-biomass experiments demonstrated limited aerobic and relatively higher anoxic nitrate and nitrite reduction capabilities; the highest NO2-N and NO3-N removal rates were 1.3 ±â€¯0.1 and 0.74 ±â€¯0.01 in aerobic and 1.4 ±â€¯0.05 and 3.4 ±â€¯0.1 mg/L.h in anoxic media, respectively. Key potential denitrifiers were identified as: (i) complete aerobic denitrifiers: Dokdonella, Flavobacterium, and Ca. Accumulibacter; (ii) complete anoxic denitrifiers: Acinetobacter, Pseudomonas, Arcobacter, and Comamonas; (iii) incomplete nitrite denitrifier: Diaphorobacter (aerobic/anoxic), (iv): incomplete nitrate denitrifiers: Thauera (aerobic/anoxic) and Zoogloea (strictly-aerobic). Granular biomass removed 72 mg/L NH4-N with no NOx- accumulation. Heterotrophic nitrification and aerobic denitrification were proposed as the principal nitrogen removal pathway in granular reactors, potentially performed by two key organisms Thuaera and Flavobacterium. Biodiversity analysis suggested that the selection pressure of nourishment condition was the decisive factor for microbial selection and nitrogen removal mechanism.

Influence of operation mode and wastewater strength on aerobic granulation at pilot scale: Startup period, granular sludge characteristics, and effluent quality.

This study attempted to investigate the influence of operation mode and wastewater strength on startup period, aerobic granular sludge (AGS) characteristics, and system effluent quality at pilot scale. Granulation was monitored in three pilot-scale granular sequencing batch reactors (GSBRs). Comparative evaluation of AN/O/AX/O_SBR and O_SBR, fed with wastewater of the same composition but run with completely different SBR reaction phase arrangements (alternating vs. purely aerobic), revealed the effect of SBR operation mode. Comparative study of the GSBRs operated with alternating SBR reaction phases (AN/O/AX/O_SBR and AN/O_SBR) and fed with wastewater of different strength (high- vs. medium-strength) determined the effect of wastewater composition. Granulation time and granule size were regulated by wastewater strength and the resulting organic and sludge loading conditions. Whereas, AGS morphology, granule structure, and floccular proportion of AGS were attributed to SBR operation mode. Effluent clarity in terms of suspended solid concentration depended on wastewater strength. Subtle but distinct microbial selection strategies were in effect during granulation which were also imposed by wastewater strength. Due to strong correlation between the effluent and AGS microbial structures, demonstrated by biodiversity analysis, differences in the microbial composition of effluent biomass and washout patterns of the GSBRs could be explained by wastewater strength as well. Limited nutrient removal efficiencies, restricted by organic matter concentration, could be due to involvement of unorthodox nutrient removal pathways which warrants further investigation.

Influence of UV dose on the UV/H2O2 process for the degradation of carbamazepine in wastewater.

This study evaluates the influence of UV dose on degradation of carbamazepine (CBZ) in wastewater under UV-C (λ = 254 nm) photolysis with and without H2O2. The rate of degradation of CBZ exhibited a direct dependence on the intensity of incident UV irradiation as the rate of degradation was observed to increase linearly (R2 = 0.98) with UV intensity between 1.67 and 8.95 × 1017 photons/s. More than 95% of the CBZ that spiked in wastewater rapidly degraded within 4 min with a first-order rate constant of 1.2 min-1 for an optimum H2O2 dose of 100 mg/L. Bench-scale continuous flow reactor experiments also showed that CBZ degraded with first-order kinetics at a rate constant of 1.02 min-1. The kinetic parameters obtained for a continuous bench-scale reactor were in good agreement with the relationships developed through batch experiments with only a marginal deviation of ± 6.5%. The relationship between UV intensity and CBZ degradation rate obtained in this study was extrapolated to the UV disinfection unit of a wastewater treatment plant to predict possible degradation of CBZ during UV disinfection. The addition of 100 mg/L of H2O2 to the secondary-treated effluent entering the UV disinfection unit is predicted to achieve over 60% degradation of CBZ. Abbreviations: CBZ carbamazepine; AOPs advanced oxidation processes; UV ultraviolet radiation; UV-C ultraviolet C (λ = 254 nm) radiation; NZVI non-zerovalent iron; WWTP wastewater treatment plant; HPLC high-performance liquid chromatography.