Enhancing the oxygen evolution reaction activity of CuCo based hydroxides with V2CT x MXene.

The oxygen evolution reaction (OER) is a key reaction in the production of green hydrogen by water electrolysis. In alkaline media, the current state of the art catalysts used for the OER are based on non-noble metal oxides. However, despite their huge potential as OER catalysts, these materials exhibit various disadvantages including lack of stability and conductivity that hinder the wide-spread utilization of these materials in alkaline electrolyzer devices. This study highlights the innovative chemical functionalization of a mixed copper cobalt hydroxide with the V2CT x MXene to enhance the OER efficiency, addressing the need for effective electrocatalytic interfaces for sustainable hydrogen production. The herein synthesized CuCo@V2CT x electrocatalysts demonstrate remarkable activity, outperforming the pure CuCo catalysts for the OER and moreover show increased efficiency after 12 hours of continuous operation. This strategic integration improved the water oxidation performance of the pure oxide material by improving the composite's hydrophilicity, charge transfer properties and ability to hinder Cu leaching. The materials were characterized using an array of materials characterization techniques to help decipher both structure of the composite materials after synthesis and to elucidate the reasoning for the OER enhancement for the composites. This work demonstrates the significant potential of TMO-based nanomaterials combined with V2CT x for advanced innovative electrocatalytic interfaces in energy conversion applications.

Transparent Conductors Printed from Grids of Highly Conductive Silver Nanosheets.

Transparent conductors (TCs) represent key components in many applications from optoelectronic devices to electromagnetic shielding. While commercial applications typically use thin films of indium tin oxide, this material is brittle and increasingly scarce, meaning higher performing and cheaper alternatives are sought after. Solution-processible metals would be ideal owing to their high conductivities and printability. However, due to their opacity to visible light, such films need to be very thin to achieve transparency, thus limiting the minimum resistance achievable. One solution is to print metallic particles in a grid structure, which has the advantages of high tunable transparency and resistance at the cost of uniformity. Here, we report silver nanosheets that have been aerosol jet printed into grids as high-performance transparent conductors. We first investigate the effect of annealing on the silver nanosheets where we observe the onset of junction sintering at 160 °C after which the silver network becomes continuous. We then investigate the effect of line width and thickness on the electrical performance and the effect of varying the aperture dimensions on the optical performance. Using these data, we develop simple models, which allow us to optimize the grid and demonstrate a printed transparent conductor with a transmittance of 91% at a sheet resistance of 4.6 Ω/sq.