Investigation of the Solubility of Elemental Sulfur (S) in Sulfur-Containing Natural Gas with Machine Learning Methods.

Some natural gases are toxic because they contain hydrogen sulfide (H2S). The solubility pattern of elemental sulfur (S) in toxic natural gas needs to be studied for environmental protection and life safety. Some methods (e.g., experiments) may pose safety risks. Measuring sulfur solubility using a machine learning (ML) method is fast and accurate. Considering the limited experimental data on sulfur solubility, this study used consensus nested cross-validation (cnCV) to obtain more information. The global search capability and learning efficiency of random forest (RF) and weighted least squares support vector machine (WLSSVM) models were enhanced via a whale optimization-genetic algorithm (WOA-GA). Hence, the WOA-GA-RF and WOA-GA-WLSSVM models were developed to accurately predict the solubility of sulfur and reveal its variation pattern. WOA-GA-RF outperformed six other similar models (e.g., RF model) and six other published studies (e.g., the model designed by Roberts et al.). Using the generic positional oligomer importance matrix (gPOIM), this study visualized the contribution of variables affecting sulfur solubility. The results show that temperature, pressure, and H2S content all have positive effects on sulfur solubility. Sulfur solubility significantly increases when the H2S content exceeds 10%, and other conditions (temperature, pressure) remain the same.

Intelligent identification of natural gas pipeline defects based on improved pollination algorithm.

As a natural gas pipeline approaches the end of its service life, the integrity of the pipeline starts failing because of corrosion or cracks. These and other defects affect the normal production and operation of the pipeline. Therefore, the identification of pipeline defects is critical to ensure the normal, safe, and efficient operation of these pipelines. In this study, a combination of adaptive adjustment based on conversion probability and Gaussian mutation strategy was used to improve the flower pollination algorithm (FPA) and enhance the search ability of traditional flower pollination. The adaptive adjustment of the transition probability effectively balances the development and exploration abilities of the algorithm. The improved flower pollination algorithm (IFPA) outperformed six classical benchmark functions that were used to verify the superiority of the improved algorithm. A Gaussian mutation strategy was integrated with IFPA to optimise the initial input weights and thresholds of the extreme learning machine (ELM), improve the balance and exploration ability of the algorithm, and increase the efficiency and accuracy for identifying pipeline defects. The proposed IFPA-ELM model for pipeline defect identification effectively overcomes the tendency of FPA to converge to local optima and that of ELM to engage in overfitting, which cause poor recognition accuracy. The identification rates of various pipeline defects by the IFPA-ELM algorithm are 97% and 96%, which are 34% and 13% higher, respectively, than those of FPA and FPA-ELM. The IFPA-ELM model may be used in the intelligent diagnosis of pipeline defects to solve practical engineering problems. Additionally, IFPA could be further optimised with respect to the time dimension, parameter settings, and general adaptation for application to complex engineering optimisation problems in various fields.

Modeling the Solubility of Sulfur in Sour Gas Mixtures Using Improved Support Vector Machine Methods.

The study of sulfur solubility is of great significance to the safe development of sulfur-containing gas reservoirs. However, due to measurement difficulties, experimental research data on sulfur solubility thus far are limited. Under the research background of small samples and poor information, a weighted least-squares support vector machine (WLSSVM)-based machine learning model suitable for a wide temperature and pressure range is proposed to improve the prediction accuracy of sulfur solubility in sour gas. First, we use the comprehensive gray relational analysis method to extract important factors affecting sulfur solubility as the model input parameters. Then, we use the whale optimization algorithm (WOA) and gray wolf optimizer (GWO) intelligence algorithms to find the optimal solution of the penalty factor and kernel coefficient and bring them into three common kernel functions. The optimal kernel function is calculated, and the final WOA-WLSSVM and GWO-WLSSVM models are established. Finally, four evaluation indicators and an outlier diagnostic method are introduced to test the proposed model's performance. The empirical results show that the WOA-WLSSVM model has better performance and reliability; the average absolute relative deviation is as low as 3.45%, determination coefficient (R 2) is as high as 0.9987, and the prediction accuracy is much higher than that of other models.