Detalhe da pesquisa
1.
Entropic intermediates and hidden rate-limiting steps in seemingly concerted cycloadditions. Observation, prediction, and origin of an isotope effect on recrossing.
J Am Chem Soc
; 134(4): 1914-7, 2012 Feb 01.
Artigo
em Inglês
| MEDLINE | ID: mdl-22229840
2.
Isotope effect, mechanism, and origin of catalysis in the decarboxylation of mandelylthiamin.
J Am Chem Soc
; 132(20): 6896-7, 2010 May 26.
Artigo
em Inglês
| MEDLINE | ID: mdl-20433168
3.
Experimental evidence for heavy-atom tunneling in the ring-opening of cyclopropylcarbinyl radical from intramolecular 12C/13C kinetic isotope effects.
J Am Chem Soc
; 132(36): 12548-9, 2010 Sep 15.
Artigo
em Inglês
| MEDLINE | ID: mdl-20722415