Light modulation with electro-optic polymer-based resonant grating waveguide structures.

A novel modulator design incorporating an E-O polymer into a resonant grating waveguide structure is presented. Using purely polymeric material we developed a resonant grating waveguide structure having low loss and high finesse, with approximately 2nm spectral line width at 1.55 mum. An externally applied voltage modulates the refractive index of the E-O waveguide, thereby shifting the resonance wavelength and modulating the incident light at MHz rates. Such modulator operates in free space and does not involve waveguide patterning nor the need for facet conditioning and coupling common to operation in the Mach-Zehnder type configuration.

A novel microfluidic flow-injection analysis device with fluorescence detection for cation sensing. Application to potassium.

A microfabricated device has been developed for fluorimetric detection of potassium ions without previous separation. It is based on use of a fluorescent molecular sensor, calix-bodipy, specially designed to be sensitive to and selective for the target ion. The device is essentially made of a Y-shape microchannel moulded in PDMS fixed on a glass substrate. A passive mixer is used for mixing the reactant and the analyte. The optical detection arrangement uses two optical fibres, one for excitation by a light-emitting diode, the other for collection of the fluorescence. This system enabled the flow-injection analysis of the concentration of potassium ions in aqueous solutions with a detection limit of 0.5 mmol L(-1) and without interference with sodium ions. A calibration plot was constructed using potassium standard solutions in the range 0-16 mmol L(-1), and was used for the determination of the potassium content of a pharmaceutical pill. Figure Photography of the microfluidic channel showing the ridges in the PDMS substrate at the top of the channel.

Simple interferometric technique for generation of a radially polarized light beam.

We present a theoretical and experimental investigation of an interferometric technique for converting a linearly polarized Gaussian beam into a radially polarized doughnut beam. The experimental setup accomplishes the coherent summation of two orthogonally polarized TEM01 and TEM10 beams that are obtained from the transformation of a TEM00 beam by use of a simple binary diffractive optical element. We have shown that the degree of radial polarization is maximum at a given distance from the interferometer output port that depends on the diameter of the incident beam at the interferometer input port.

Design and synthesis of push-pull chromophores for second-order nonlinear optics derived from rigidified thiophene-based pi-conjugating spacers.

Two series of push-pull chromophores built around thiophene-based pi-conjugating spacers rigidified either by covalent bonds or by noncovalent intramolecular interactions have been synthesized and characterized by UV-vis spectroscopy, electric field induced second harmonic generation (EFISH) and differential scanning calorimetry. Comparison of the linear and second-order nonlinear optical properties of chromophores based on a covalently bridged dithienylethylene (DTE) spacer with those of their analogues based on open chain DTE shows that the rigidification of the spacer produces a considerable bathochromic shift of the absorption maximum together with a dramatic enhancement of the molecular quadratic hyperpolarizability (mu beta) which reaches values among the highest reported so far. A second series of NLO-phores has been derived from a 2,2'-bi(3,4-ethylenedioxythiophene) (BEDOT) pi-conjugating spacer. As indicated by X-ray and UV-vis data, rigidification of the spacer originates in that case, from noncovalent intramolecular interactions between sulfur and oxygen atoms. Again, comparison with the parent compounds based on an unsubstituted bithiophene spacer reveals a marked red shift of the absorption maximum and a large enhancement of mu beta. In an attempt to distinguish the contribution of the electronic and geometrical effects of the ethylenedioxy group, a third series of NLO-phores based on 3,4-ethylenedioxythiophene (EDOT) and 3,4-dihexyloxythiophene spacers has been synthesized. Comparison with compounds based on unsubstituted thiophene shows that, despite a red shift of lambda(max), introduction of alkoxy groups leads to a decrease of mu beta. Theoretical calculations indicate that this effect results from a decrease of the dipole moment (mu) caused by the auxiliary electron-donor alkoxy groups on the thiophene ring. In contrast, replacement of BT by BEDOT produces an increase of mu, which associated with the noncovalent rigidification of the BT system accounts for the observed enhancement of mu beta.