Are hydrides under high-pressure-high-temperature superconductors?

Contrary to the current consensus, I argue that the existing evidence for high-temperature superconductivity in hydrides under high pressure is not compelling. I suggest that the focus of the field should urgently shift to establish unequivocally experimentally whether or not superconductivity in pressurized hydrides exists, instead of continuing to search for new materials that might show elusive signals of unproven superconductivity at ever higher temperatures. The implications of a negative finding for the theoretical understanding of superconductivity are discussed.

On Thermal and Electrodynamic Aspects of the Superconductive Transition Process.

In a classic paper of 1960, W. H. Cherry and J. I. Gittleman discussed various thermal and electrodynamic aspects of the superconductive transition process relevant to practical applications. In a section of the paper that has remained unnoticed, they proposed a physical model for the Meissner effect. Earlier in 1940-1943, in work that has also remained unnoticed, K. M. Koch had introduced related physical ideas to explain the Meissner effect. Still earlier in 1937, J. C. Slater proposed a model to explain the perfect diamagnetism of superconductors. None of these ideas are part of the conventional London-BCS understanding of superconductivity, yet I will argue that they are essential to understand the Meissner effect, the most fundamental property of superconductors. The unconventional theory of hole superconductivity unifies and extends these ideas. A key missing element in the conventional theory as well as in these early theories is electron-hole asymmetry. A proper understanding of the Meissner effect may help with practical applications of superconductors, as well as to find new superconducting materials with desirable properties.

Comment on "Carbon content drives high temperature superconductivity in a carbonaceous sulfur hydride below 100 GPa" by G. A. Smith, I. E. Collings, E. Snider, D. Smith, S. Petitgirard, J. S. Smith, M. White, E. Jones, P. Ellison, K. V. Lawler, R. P. Dias and A. Salamat, Chem. Commun., 2022, 58, 9064.

Experimental data supporting the claim that a carbonaceous sulfur hydride (CSH) under pressure is a high temperature superconductor were presented. Here we report results of a mathematical analysis that indicates that with probability larger than 1-10-338 some of those data were not measured in a laboratory, contrary to what the papers claim. This finding undermines confidence in the claim that any of the experimental evidence reported in those papers reflects the properties of real physical samples of CSH.

Does the H index have predictive power?

Bibliometric measures of individual scientific achievement are of particular interest if they can be used to predict future achievement. Here we report results of an empirical study of the predictive power of the h index compared with other indicators. Our findings indicate that the h index is better than other indicators considered (total citation count, citations per paper, and total paper count) in predicting future scientific achievement. We discuss reasons for the superiority of the h index.

The missing angular momentum of superconductors.

We point out that the Meissner effect, the process by which a superconductor expels magnetic field from its interior, represents an unsolved puzzle within the London-Bardeen-Cooper-Schrieffer theoretical framework used to describe the physics of conventional superconductors, because it appears to give rise to non-conservation of angular momentum. Possible ways to avoid this inconsistency within the conventional theory of superconductivity are argued to be far-fetched. Consequently, we argue that unless/until a consistent explanation is put forth, the existence of the Meissner effect represents an anomaly that casts doubt on the validity of the conventional framework. Instead, we point out that three elements of the unconventional theory of hole superconductivity (that are not part of the conventional theory) allow for a consistent explanation of the Meissner effect, namely: (i) that the charge distribution in superconductors is macroscopically inhomogeneous, (ii) that superconducting electrons reside in mesoscopic orbits of radius 2λ(L) (λ(L) = London penetration depth), and (iii) that spin-orbit coupling plays an essential role in superconductivity.

Ventilation response and drive during hypoxia in adult patients with asthma.

We studied ventilation and inspiratory muscle activity during progressive isocapnic hypoxia in adult asthmatic patients to determine whether the decreased hypoxic ventilatory response previously identified is due to the mechanical abnormalities of the respiratory system or to low respiratory center output. The mouth pressure produced by inspiratory muscle activity, a reflection of respiratory center output, was measured at 100 msec of inspiration against an occluded airway at functional residual capacity. At end-tidal oxygen tension (PETO2) of 80 mm Hg, inspiratory muscle activity was greater in asthmatic patients than in normal subjects for the same level of ventilation, but at PETO2 of 40 mm Hg, both inspiratory muscle activity and ventilation were lower in asthmatic patients. Consequently, the changes in inspiratory muscle activity and ventilation per mm Hg change in PETO2 were lower in the asthmatic patients. To generate the same ventilation during progressive hypoxia, more inspiratory muscle activity was needed by asthmatic patients. We concluded that the decreased hypoxic ventilation in asthmatic patients resulted from both decreased respiratory center output and from mechanical abnormalities of the respiratory system.

Hearing screening in the newborn intensive care nursery: comparison of methods.

Patients in the neonatal intensive care unit were tested by hearing screening tests including auditory brain stem response (ABR), transient and distortion-product otoacoustic emissions (TEOAEs and DPOAEs), and acoustic stapedius reflex (ASR), and by middle ear function tests including multifrequency tympanometry and pneumatic otoscopy. Pass rates on hearing tests were 75% to 89%. TEOAEs produced the lowest pass rate, and DPOAEs the highest. TEOAE, DPOAE, or ASR testing followed by ABR testing of initial failures produced pass rates of about 90%. The most efficient combination was DPOAEs followed by ABR. Pass rates tended to decrease with age. Of patients who failed 226-Hz and 678-Hz tympanometry, 30% to 67% passed hearing tests, suggesting a high false-positive rate for these immittance tests. The 3 ears that failed the 1000-Hz tympanogram failed all hearing tests. Many ears were abnormal by pneumatic otoscopy but passed hearing tests, suggesting that the usual ear examination criteria may not apply to infants.

Early- and middle-aer components to clicks as response indices for neonatal hearing screening.

Early- and middle-component-averaged electroencephalic responses (AER) to monotic clicks at 60, 40 and 20 dB normal hearing level were elicited from 18 carefully selected normal neonates. Grand-composite AERs of the responses from all 18 babies showed stimulus-related configurations at all three stimulus levels. AERs for individual babies were more frequently identified as stimulus-related when poststimulus activity beyond 10 ms was included in response-identification procedures than when only the first 10 ms was observed.

Apparent increase in the thickness of superconducting particles at low temperatures measured by electron holography.

We predict that superconducting particles will show an apparent increase in thickness at low temperatures when measured by electron holography. This will result not from a real thickness increase, rather from an increase in the mean inner potential sensed by the electron wave traveling through the particle, originating in expansion of the electronic wavefunction of the superconducting electrons and resulting negative charge expulsion from the interior to the surface of the superconductor, giving rise to an increase in the phase shift of the electron wavefront going through the sample relative to the wavefront going through vacuum. The temperature dependence of the observed phase shifts will yield valuable new information on the physics of the superconducting state of metals.

Explanation of the Tao effect: theory for the spherical aggregation of superconducting microparticles in an electric field.

In a series of experiments Tao and co-workers found that superconducting microparticles in the presence of a strong electrostatic field aggregate into balls of macroscopic dimensions. No explanation of this phenomenon exists within the conventional theory of superconductivity. We show that this effect can be understood within an alternative electrodynamic description of superconductors recently proposed that follows from an unconventional theory of superconductivity. Experiments to test the theory are discussed.

An index to quantify an individual's scientific research output.

I propose the index h, defined as the number of papers with citation number > or =h, as a useful index to characterize the scientific output of a researcher.

Predicted electric field near small superconducting ellipsoids.

We predict the existence of large electric fields near the surface of superconducting bodies of ellipsoidal shape of dimensions comparable to the penetration depth. The electric field is quadrupolar in nature with significant corrections from higher order multipoles. Prolate (oblate) superconducting ellipsoids are predicted to exhibit fields consistent with negative (positive) quadrupole moments, reflecting the fundamental charge asymmetry of matter.

Dynamic Hubbard model.

The Hubbard on-site repulsion U between opposite spin electrons on the same atomic orbital is widely regarded to be the most important source of electronic correlation in solids. Here we extend the Hubbard model to account for the fact that the experimentally measured atomic U is different from the one obtained by calculation of the atomic Coulomb integral. The resulting model describes quasiparticles that become increasingly dressed as the number of electrons in the band increases. Superconductivity can result in this model through quasiparticle undressing. Various signatures of this physics in spectroscopies in the normal and superconducting states are discussed. A novel effect in the normal state is predicted to be electroluminescence at the sample-positive counterelectrode boundary.

The effect of middle ear pressure on transient evoked otoacoustic emissions.

To determine the effect of middle ear pressure on transient evoked otoacoustic emissions (TEOAEs), emissions were recorded in ears with tympanometric peak pressures < or = -100 daPa and audiometric thresholds < or = 30 dB HL at 500 through 2000 Hz. TEOAEs were alternately recorded at ambient pressure and at the tympanometric peak pressure. As demonstrated for the 14 ears tested, equalization of the middle ear pressure increased TEOAE amplitude. Reproducibility was similarly improved in 12 of 14 ears. Unequalized middle ear pressure attenuated low frequency emissions more than high frequency emissions. These amplitude and spectrum differences were consistent with previously reported observations of the effects of ear canal pressure on otoacoustic emissions. Results suggest that unequalized middle ear pressure may increase the occurrence of false positive failures, if otoacoustic emission testing is used for hearing screenings without consideration of middle ear pressure.

A comparison of acoustic reflex and auditory brain stem response screening of high-risk infants.

This investigation was undertaken to explore the feasibility of screening for hearing impairment in an intensive care nursery population with a combined acoustic stapedius reflex-ABR approach. Acoustic reflex threshold measurements (AR) were made on intensive care nursery patients in an existing ABR screening program. Pass-fail results were determined for the two methods, separately and in combination. AR screening identified all 10 ears that failed the ABR screen. The cost savings of screening with a combined AR-ABR approach was determined for various pass-fail criteria. The results suggest that the AR-ABR approach can produce a significant cost savings without compromising the sensitivity and specificity of the screening program.