A water-soluble conjugated polyelectrolyte for selective and sensitive detection of carcinogenic chromium(VI).

Environmental water pollution caused by hexavalent chromium (Cr(VI)) is a threat to living beings due to its carcinogenic nature. Herein, we report the synthesis of a highly fluorescent water-soluble conjugated polyelectrolyte PPMI and its application as a fluorescence sensor to monitor traces of carcinogenic Cr(VI) ions in water. PPMI was synthesized via the oxidative polymerization method followed by post-polymer functionalization. Fluorescent PPMI exhibited a photoluminescence quantum yield of 23.87 and displayed a rapid, very selective, and sensitive turn-off fluorescence signal in response to Cr(VI), with a significantly high quenching constant of 1.32 × 106 M-1. The mechanism of sensing was found to be static quenching. The limit of detection of this highly accessible analytical method was found to be in nanomolar ranges, i.e. 0.85 nM. Additionally, sensing on solid platforms such as economical paper strips was successfully achieved, which is very challenging and highly recommended for any reliable, portable, and economical analytical method.

Robust and multifunctional nanosheath for chemical and biological nanodevices.

The contribution of advanced nanoscale chemical and biological devices to life science has been limited to a small number of nanomaterials, due to the absence of effective surface modification routes. Herein, we demonstrate a polymer-like nanosheath synthesized by nonthermal plasma technology (NPT) that can protect the core nanomaterial from the solution environment and provide a multifunctional platform for chemical and biological nanosensors. For ZnO nanowires (NWs) which are unstable in solution, we demonstrate that this nanosheath makes it possible for ZnO NW field-effect transistors to act as a pH sensor for 24 h and a biosensor for the real-time, label-free detection of liver cancer markers.

A method to generate soft shadows using a layered depth image and warping.

We present an image-based method for propagating area light illumination through a Layered Depth Image (LDI) to generate soft shadows from opaque and nonrefractive transparent objects. In our approach, using the depth peeling technique, we render an LDI from a reference light sample on a planar light source. Light illumination of all pixels in an LDI is then determined for all the other sample points via warping, an image-based rendering technique, which approximates ray tracing in our method. We use an image-warping equation and McMillan's warp ordering algorithm to find the intersections between rays and polygons and to find the order of intersections. Experiments for opaque and nonrefractive transparent objects are presented. Results indicate our approach generates soft shadows fast and effectively. Advantages and disadvantages of the proposed method are also discussed.

Effect of chemically reactive species on properties of ZnO nanowires exposed to oxygen and hydrogen plasma.

We present a systematic study on the effect of oxygen and hydrogen plasma-generated reactive species on the properties of ZnO nanowires. Upon exposure to oxygen plasma, the electrical conductivity of an individual ZnO nanowire decreased with substantial changes in the surface chemistry, indicating a decrease in the number of donor-like defects and an increase in the number of electron-trapping species. In contrast, an individual ZnO nanowire exposed to hydrogen plasma showed a drastic increase in conductivity up to two orders of magnitude due to the incorporated hydrogen acting as a shallow donor inside the ZnO nanowires without a sputtering process.