Removal of diethyl phthalate from water by ozone microbubbles in a pilot plant.

Ozone microbubbles (OMBs) were used to remove diethyl phthalate (DEP) from water in a pilot plant. The removal of DEP and the mineralization efficiency were investigated under various reaction conditions. The removal of DEP by OMBs was very effective at the high pH and high ozone generation rates. Almost complete mineralization of DEP could be achieved at the high pH. The contribution of OH was computed by using a hydroxyl radical scavenger (i.e. t-BuOH). In neutral and alkaline media, the reaction of DEP with OH dominated over its direct reaction with ozone. The overall oxidation reaction fitted a second-order kinetic model. The overall rate constant and the volumetric mass transfer coefficient of ozone slightly increased with increasing pH. The results indicate that the OMBs were efficient in terms of the reduction of concentration of DEP and its complete mineralization.

Plasmon-based colorimetric assay using green synthesized gold nanoparticles for the detection of bisphenol A.

Herein, we report a green synthesized gold nanoparticle (AuNPs) based colorimetric detection of bisphenol A (BPA). The AuNPs were synthesized using khat leaf extract as a reducing agent by optimizing factors affecting the AuNPs synthesis, including gold precursor concentration (1 mM), and reaction temperature (60 °C). The AuNPs characterization was carried out using ultraviolet-visible spectrophotometry and transmission electron microscopy, and it was found spherical with an average particle size of 17.3 ± 3.7 nm. A colorimetric nanosensor was developed by conjugation of bio-inspired AuNPs with BPA-specific aptamer for a quick and easy detection of BPA in plastic bottled water. The colorimetric assay relies on the strong affinity of BPA for aptamer, which causes detachment of the aptamer from the AuNPs surface in the presence of BPA inducing AuNPs aggregation. To achieve the colorimetric detection of BPA, the concentrations of NaCl and aptamer were optimized. The detection of BPA was monitored visually using a naked eye, as well as quantitatively using an ultraviolet-visible spectrophotometer. The method visual limit of detection (LOD) was determined to be 0.1 ng/mL and reached 0.09 ng/mL using ultraviolet-visible spectrophotometer. The method demonstrated very good linearity (R2 = 0.9986) in the range of 0.1-100 ng/mL. The proposed method showed high sensitivity to BPA detection in plastic bottled water with 86.7-98.0%, recovery. Therefore, the proposed colorimetric nanosensor can be used for determination of BPA in plastic bottled waters with reliable performance at lower concentrations.

Adsorptive performances and valorization of green synthesized biochar-based activated carbon from banana peel and corn cob composites for the abatement of Cr(VI) from synthetic solutions: Parameters, isotherms, and remediation studies.

This study intended to remove Cr(VI) from an aqueous synthetic solution employing synthesized biochar adsorbent from a blend of locally sourced banana peel, and corn cob biomass wastes. An equal ratio of the prepared powder was activated with ZnCl2 solution (1:1 wt basis) and carbonized for 2 h at 600 °C. The proximate analysis of the selected BP-CCAC@ZC3 biochar was conducted. Subsequently, its surface area, surface functions, and morphology were examined using BET analysis, FTIR, and SEM techniques, respectively. The proximate analysis of BP-CCAC@ZC3 showed a moisture content of 2.37 ± 0.80 %, an ash content of 8.07 ± 0.75 %, volatile matter of 19.38 ± 2.66 %, and fixed carbon of 70.18 %. It was found that the synthesized BP-CCAC@ZC3 had 432.149 m2/g of a specific area as per the BET surface area analysis. The highest efficiency for Cr(VI) removal was determined to be 97.92 % through adsorption batch tests using a dose of 0.4 g of BP-CCAC@ZC3, an initial Cr(VI) concentration of 20 mg/L, pH of 2, and 35 min contact time. Likewise, the adsorption process was effectively described by the Langmuir isotherm model, which had a high correlation coefficient (R 2 = 0.9977) and a maximum adsorption capacity of 19.16 mg/g, indicating a monolayer adsorption mechanism. The BP-CCAC@ZC3 biochar exhibited reusability for up to four cycles with only a slight decrease in effectiveness, highlighting its potential for sustainable wastewater treatment. Overall, using corn cob and banana peel composites to synthesize activated carbon with ZnCl2 offers a promising method for effectively removing Cr(VI) containing wastewater.

Comprehensive review on lignocellulosic biomass derived biochar production, characterization, utilization and applications.

Biochar is an ample source of organic carbon prepared by the thermal breakdown of biomass. Lignocellulosic biomass is a promising precursor for biochar production, and has several applications in various industries. In addition, biochar can be applied for environmental revitalization by reducing the negative impacts through intrinsic mechanisms. In addition to its environmentally friendly nature, biochar has several recyclable and inexpensive benefits. Nourishing and detoxification of the environment can be undertaken using biochar by different investigators on account of its excellent contaminant removal capacity. Studies have shown that biochar can be improved by activation to remove toxic pollutants. In general, biochar is produced by closed-loop systems; however, decentralized methods have been proven to be more efficient for increasing resource efficiency in view of circular bio-economy and lignocellulosic waste management. In the last decade, several studies have been conducted to reveal the unexplored potential and to understand the knowledge gaps in different biochar-based applications. However, there is still a crucial need for research to acquire sufficient data regarding biochar modification and management, the utilization of lignocellulosic biomass, and achieving a sustainable paradigm. The present review has been articulated to provide a summary of information on different aspects of biochar, such as production, characterization, modification for improvisation, issues, and remediation have been addressed.

Bioethanol production from agricultural residues as lignocellulosic biomass feedstock's waste valorization approach: A comprehensive review.

Bioenergy is becoming very popular, drawing attention as a renewable energy source that may assist in managing growing energy costs, besides possibly affording revenue to underprivileged farmers and rural populations worldwide. Bioethanol made from agricultural residual-biomass provides irreplaceable environmental, socioeconomic, and strategic benefits and can be considered as a safe and cleaner liquid fuel alternative to traditional fossil fuels. There is a significant advancement made at the bench scale towards fuel ethanol production from agricultural lignocellulosic materials (ALCM). These process technologies include pretreatment of ALCM biomass employment of cellulolytic enzymes for depolymerizing carbohydrate polymers into fermentable sugars to effectively achieve it by applying healthy fermentative microbes for bioethanol generation. Amongst all the available process methods, weak acid hydrolysis followed by enzymatic hydrolysis process technique. Recovering higher proficient celluloses is more attractive in terms of economic benefits and long-term environmental effects. Besides, the state of ALCM biomass based bioethanol production methods is discussed in detail, which could make it easier for the scientific and industrial communities to utilize agricultural leftovers properly.

Removal of dimethyl phthalate from water by ozone microbubbles.

This work investigates the removal of dimethyl phthalate (DMP) from water using ozone microbubbles in a pilot plant of 20 dm3 capacity. Experiments were performed under various reaction conditions to examine the effects of the initial concentration of DMP, pH of the medium, ozone generation rate, and the role of H2O2 on the removal of DMP. The DMP present in water was effectively removed by the ozone microbubbles. The removal was effective in neutral and alkaline media. Increase in the initial concentration of the target pollutant negatively affected its removal efficiency. The removal efficiency dramatically increased from 1% to 99% when the ozone generation rate was increased from 0.28 to 1.94 mg s-1 at pH 7. The total organic carbon measurements revealed that a complete mineralization of DMP was achieved within 1.8 ks at the high ozone feed rate. The use of t-butyl alcohol as the hydroxyl radical scavenger confirmed that the reaction between the target organic compound and ·OH radical dominated over its direct reaction with ozone. The reaction between DMP and ozone followed an overall second-order kinetics. The volumetric mass transfer coefficient of ozone in the reacting system and the enhancement factor increased with increasing initial concentration of DMP. Very low values of Hatta number were obtained at all initial concentrations of DMP and pH, which show that the mass transfer resistance was small.