Dual Josephson Impedance Bridge: Towards a Universal Bridge for Impedance Metrology.

This paper presents a full characterization of a Dual Josephson Impedance Bridge (DJIB) at frequencies up to 80 kHz by using the DJIB to compare the best available impedance standards that are (a) directly traceable to the quantum Hall effect, (b) used as part of international impedance comparisons, or (c) believed to have calculable frequency dependence. The heart of the system is a dual Josephson Arbitrary Waveform Synthesizer (JAWS) source that offers unprecedented flexibility in high-precision impedance measurements. The JAWS sources allow a single bridge to compare impedances with arbitrary ratios and phase angles in the complex plane. The uncertainty budget shows that both the traditional METAS bridges and the DJIB have comparable uncertainties in the kilohertz range. This shows that the advantages of the DJIB, including the flexibility which allows the comparison of arbitrary impedances, the wide frequency range, and the automated balancing procedure, are obtained without compromising the measurement uncertainties. These results demonstrate that this type of instrument can considerably simplify the realization and maintenance of the various impedance scales. In addition, the DJIB is a very sensitive tool for investigating the frequency-dependent systematic-errors that can occur in impedance construction and in the voltage provided by the JAWS source at frequencies greater than 10 kHz.

Restoring the Electrical Properties of CVD Graphene via Physisorption of Molecular Adsorbates.

Chemical vapor deposition (CVD) is a powerful technique to produce graphene for large-scale applications. Polymer-assisted wet transfer is commonly used to move the graphene onto silicon substrates, but the resulting devices tend to exhibit p-doping, which decreases the device quality and reproducibility. In an effort to better understand the origin of this effect, we coated graphene with n-methyl-2-pyrrolidone (NMP) and hexamethyldisilazane (HMDS) molecules that exhibit negligible charge transfer to graphene but bind more strongly to graphene than ambient adsorbents. Using Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), electrical transport measurements, and quantum mechanical computer simulations, we show that the molecules help in the removal of p-doping, and our data indicate that the molecules do this by replacing ambient adsorbents (typically O2 and water) on the graphene surface. This very simple method of improving the electronic properties of CVD graphene by passivating its surface with common solvent molecules will accelerate the development of CVD graphene-based devices.