Nontrivial ultraslow dynamics under electric-field in nematics of bent-shaped molecules.

For over decades, nematic liquid crystals have been recognized as highly fluidic materials that respond to electric field on the millisecond scale. In contrast to traditional nematics with fast responsivity, we herein report nontrivial ultraslow electric-driven dynamics in bent-shaped nematic materials. Varying the alkyl chain spacers of bent-shaped cyanobiphenyl dimers (COOm and OCOm) shows a 'transition' in the dynamics behavior between the bent-dimeric and bent-core materials. Interestingly, with short alkyl chain spacers, COO2 exhibits unexpected ultra-slow dynamic pathways, i.e., "quasi-static" electrohydrodynamic convection. A significant observation is that the on/off-electro-switching time of COO2 is 10 000 times higher than that of typical nematic materials, which is the largest value reported ever in the kilo-second range. In addition, the threshold voltage for inducing the reorientation of the nematic director for COO2 is higher than 5 V, which is uncommon in traditional N materials. These properties are distinct from those of traditional nematic materials and discussed in terms of dielectric constants and electrohydrodynamic convection.

Thioether-Linked Liquid Crystal Trimers: Odd-Even Effects of Spacers and the Influence of Thioether Bonds on Phase Behavior.

We report the synthesis, phase-transition behavior, and mesophase structures of the first homologous series of thioether-linked liquid crystal (LC) trimers, 4,4'-bis[ω-(4-cyanobiphenyl-4'-ylthio)alkoxy]biphenyls (CBSnOBOnSCB with a wide range of spacer carbon numbers, n = 3-11). All CBSnOBOnSCB homologs exhibited LC phases. Interestingly, even-n and odd-n homologs showed monotropic layered smectic A (SmA) and pseudo-layered twist-bend nematic (NTB) phases, respectively, below a nematic (N) phase. This alternate formation, which depends on spacer chain parity, is attributed to different average molecular shapes, which are associated with the relative orientations of the biphenyl moieties: linear and bent shapes for even-n and odd-n homologs, respectively. In addition, X-ray diffraction analysis indicated a strong cybotactic N phase tendency, with a triply intercalated structure. The phase-transition behavior and LC phase structures of thioether-linked CBSnOBOnSCB were compared with those of the all-ether-linked classic LC trimers CBOnOBOnOCB. Overall, thioether linkages endowed CBSnOBOnSCB with a monotropic LC tendency and lowered phase-transition temperatures, compared to those of CBOnOBOnOCB, for the same n. This is attributed to enhanced flexibility and bending (less molecular anisotropy) of the molecules, caused by the greater bond flexibility and smaller inner bond angles of the C-S-C bonds, compared to those of the C-O-C bonds.