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1.
Nat Commun ; 13(1): 3480, 2022 Jun 16.
Artigo em Inglês | MEDLINE | ID: mdl-35710903

RESUMO

The scientific interest in two-dimensional topological insulators (2D TIs) is currently shifting from a more fundamental perspective to the exploration and design of novel functionalities. Key concepts for the use of 2D TIs in spintronics are based on the topological protection and spin-momentum locking of their helical edge states. In this study we present experimental evidence that topological protection can be (partially) lifted by pairwise coupling of 2D TI edges in close proximity. Using direct wave function mapping via scanning tunneling microscopy/spectroscopy (STM/STS) we compare isolated and coupled topological edges in the 2D TI bismuthene. The latter situation is realized by natural lattice line defects and reveals distinct quasi-particle interference (QPI) patterns, identified as electronic Fabry-Pérot resonator modes. In contrast, free edges show no sign of any single-particle backscattering. These results pave the way for novel device concepts based on active control of topological protection through inter-edge hybridization for, e.g., electronic Fabry-Pérot interferometry.

2.
Acta Biochim Pol ; 40(4): 521-30, 1993.
Artigo em Inglês | MEDLINE | ID: mdl-7511312

RESUMO

Chemical synthesis of 2'-O-[13C]methyl-rCGCGCG and 5-methyl-rCGCGCG using support-aided phosphoramidite method is presented. 2'-O-Methyl guanosine derivative was separated from its 3'-O-methyl counterpart using transient 5',3'-O-silylation with 1,3-dichloro-1,1,3,3-tetraisopropyldisiloxane (Markiewicz reagent). The hexamers were obtained in a purity suitable for NMR studies.


Assuntos
Oligorribonucleotídeos/síntese química , RNA/síntese química , Sequência de Bases , Isótopos de Carbono , Métodos , Metilação , Conformação de Ácido Nucleico , Oligorribonucleotídeos/química , RNA/química
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