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Scattering amplitudes in quantum field theory are independent of the field parametrization, which has a natural geometric interpretation as a form of "coordinate invariance." Amplitudes can be expressed in terms of Riemannian curvature tensors, which makes the covariance of amplitudes under nonderivative field redefinitions manifest. We present a generalized geometric framework that extends this manifest covariance to all allowed field redefinitions. Amplitudes satisfy a recursion relation to all orders in perturbation theory that closely resembles the application of covariant derivatives to increase the rank of a tensor. This allows us to argue that tree-level amplitudes possess a notion of "on-shell covariance," in that they transform as a tensor under any allowed field redefinition up to a set of terms that vanish when the equations of motion and on-shell momentum constraints are imposed. We highlight a variety of immediate applications to effective field theories.
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BACKGROUND: Viral infection activates innate immune pathways and interferons (IFNs) play a pivotal role in the outcome of a viral infection. Ubiquitin modifications of host and viral proteins significantly influence the progress of virus infection. Ubiquitin-conjugating enzyme E2s (UBE2) have the capacity to determine ubiquitin chain topology and emerge as key mediators of chain assembly. METHODS: In this study, we screened the functions of 34 E2 genes using an RNAi library during Dengue virus (DENV) infection. RNAi and gene overexpression approaches were used to study the gene function in viral infection and interferon signaling. RESULTS: We found that silencing UBE2J1 significantly impaired DENV infection, while overexpression of UBE2J1 enhanced DENV infection. Further studies suggested that type I IFN expression was significantly increased in UBE2J1 silenced cells and decreased in UBE2J1 overexpressed cells. Reporter assay suggested that overexpression of UBE2J1 dramatically suppressed RIG-I directed IFNß promoter activation. Finally, we have confirmed that UBE2J1 can facilitate the ubiquitination and degradation of transcription factor IFN regulatory factor 3 (IRF3). CONCLUSION: These results suggest that UBE2 family member UBE2J1 can negatively regulate type I IFN expression, thereby promote RNA virus infection.
Assuntos
Fatores Imunológicos/metabolismo , Interferon Tipo I/metabolismo , Vírus de RNA/crescimento & desenvolvimento , Vírus de RNA/imunologia , Enzimas de Conjugação de Ubiquitina/metabolismo , Expressão Gênica , Inativação Gênica , Células HEK293 , Humanos , Interferência de RNARESUMO
The Exciplex Pumped Alkali Laser (XPAL) system, which is similar to DPAL (Diode Pumped Alkali vapor Laser), has been demonstrated in mixtures of Cs vapor, Ar, with and without ethane. Unlike DPAL, it uses the broadband absorption blue satellite of the alkali D2 line, created by naturally occuring collision pairs. For example, Cs-Ar collision pairs have an absorption width which is as wide as the one of commercial semiconductor diode lasers. A continuous wave XPAL four-level theoretical model is presented in this paper. More factors are considered, such as the spectral dependence of pumped laser absorption for broadband pumping and the longitudinal population variation. Some intra-cavity details, such as longitudinal distributions of pumped laser and alkali laser, can also be solved well. The predictions of optical-to-optical efficiency as a function of temperature and pumped laser intensity are presented. The model predicts that there is an optimum value of temperature or pumped laser intensity. The analysis of the influence of cell length on optical-to-optical efficiency shows that a better performance can be achieved when using longer cell. The prediction of influence of Ar concentration and reflectivity of output coupler shows that higher optical-to-optical efficiency could be achieved if lower reflectivity of output coupler and higher Ar concentration are used. The optical-to-optical efficiency as high as 84% achieved by optimizing configuration with the pumped intensity of 5 × 107 W/cm² presented shows that broadband pumped four-level XPAL system has a potential of high optical-to-optical efficiency.
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The Higgs mass implies fine-tuning for minimal theories of weak-scale supersymmetry (SUSY). Nondecoupling effects can boost the Higgs mass when new states interact with the Higgs boson, but new sources of SUSY breaking that accompany such extensions threaten naturalness. We show that two singlets with a Dirac mass can increase the Higgs mass while maintaining naturalness in the presence of large SUSY breaking in the singlet sector. We explore the modified Higgs phenomenology of this scenario, which we call the "Dirac next-to-minimal supersymmetric standard model."
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State-of-the-art solid-state electrolytes (SSEs) are limited in their energy density and processability based on thick, brittle pellets, which are generally hot pressed in vacuum over the course of several hours. We report on a high-throughput, open-air process for printable thin-film ceramic SSEs in a remarkable one-minute time frame using a lithium lanthanum titanium oxide (LLTO)-based SSE that we refer to as robust LLTO (R-LLTO). Powder XRD analysis revealed that the main phase of R-LLTO is polycrystalline LLTO, accompanied by selectively retained crystalline precursor phases. R-LLTO is highly dense and closely matched to the stoichiometry of LLTO with some heterogeneity throughout the film. A minimal presence of lithium carbonate is identified despite processing fully in ambient conditions. The LLTO films exhibit remarkable mechanical properties, demonstrating both flexibility with a low modulus of â¼35 GPa and a high fracture toughness of >2.0 . We attribute this mechanical robustness to several factors, including grain boundary strengthening, the presence of precursor crystalline phases, and a decrease in crystallinity or ordering caused by ultrafast processing. The creation of R-LLTO-a ceramic material with elastic properties that are closer to polymers with higher fracture toughness-enables new possibilities for the design of robust solid-state batteries.
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Solid-state sodium (Na) batteries have received extensive attention as a promising alternative to room-temperature liquid electrolyte Na-ion batteries and high-temperature liquid electrode Na-S batteries because of safety concerns. However, the major issues for solid-state Na batteries are a high interfacial resistance between solid electrolytes and electrodes, and Na dendrite growth. Here we report that a yttria-stabilized zirconia (YSZ)-enhanced beta-alumina solid electrolyte (YSZ@BASE) has an extremely low interface impedance of 3.6 Ω cm2 with the Na metal anode at 80 °C, and also exhibits an extremely high critical current density of ~7.0 mA cm-2 compared with those of other Li- and Na-ion solid electrolytes reported so far. With a trace amount of eutectic NaFSI-KFSI molten salt at the electrolyte/cathode interface, a quasi-solid-state Na/YSZ@BASE/NaNi0.45Cu0.05Mn0.4Ti0.1O2 full cell achieves a high capacity of 110 mAh g-1 with a Coulombic efficiency >99.99% and retains 73% of the cell capacity over 500 cycles at 4C and 80 °C. Extensive characterizations and theoretical calculations prove that the stable ß-NaAlO2-rich solid-electrolyte interphase and strong YSZ support matrix play a critical role in suppressing the Na dendrite as they maintain robust interfacial contacts, lower electronic conduction and prevent the continual reduction of BASE through oxygen-ion compensation.
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Reducing the operating temperature of conventional molten sodium-sulfur batteries (â¼350 °C) is critical to create safe and cost-effective large-scale storage devices. By raising the surface treatment temperature of lead acetate trihydrate, the sodium wettability on ß''-Al2O3 improved significantly at 120 °C. The low temperature Na-S cell can reach a capacity as high as 520.2 mA h g-1 and stable cycling over 1000 cycles.
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Lithium (Li) metal is a promising candidate as the anode for high-energy-density solid-state batteries. However, interface issues, including large interfacial resistance and the generation of Li dendrites, have always frustrated the attempt to commercialize solid-state Li metal batteries (SSLBs). Here, it is reported that infusing garnet-type solid electrolytes (GSEs) with the air-stable electrolyte Li3 PO4 (LPO) dramatically reduces the interfacial resistance to ≈1 Ω cm2 and achieves a high critical current density of 2.2 mA cm-2 under ambient conditions due to the enhanced interfacial stability to the Li metal anode. The coated and infused LPO electrolytes not only improve the mechanical strength and Li-ion conductivity of the grain boundaries, but also form a stable Li-ion conductive but electron-insulating LPO-derived solid-electrolyte interphase between the Li metal and the GSE. Consequently, the growth of Li dendrites is eliminated and the direct reduction of the GSE by Li metal over a long cycle life is prevented. This interface engineering approach together with grain-boundary modification on GSEs represents a promising strategy to revolutionize the anode-electrolyte interface chemistry for SSLBs and provides a new design strategy for other types of solid-state batteries.
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The formation and development of spiral defects is one of the major causes of order-disorder transitions in spatiotemporal patterns. In this paper, line defect formation and development in a three-dimensional reaction-diffusion system with gradients of control parameters in the third dimension is investigated. The system can be considered as diffusively coupled two-dimensional spatiotemporal patterns with dissimilarities. We observed that under certain conditions, as the gradients are varied, ordered and disordered spatiotemporal patterns appear alternately and line defects of various configurations form. This scenario is found to be in qualitative agreement with the experimental findings in the Belousov-Zhabotinsky reaction. We thus demonstrate that the line defect which was usually expected in two-dimensional complex oscillatory media can also be generated from the reconciliation between the coupled simple spiral waves with dissimilarity.
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With the wide usage of electronic packaging technologies such as Ball Grid Array in electronic industry, it is necessary to maintain its quality in order to meet the demand of electronic products for function, integration, and size reduction. However, as the size of solder joints in such technology decreases, the solder joints are more and more prone to defects. To solve the life prediction problem of small-size packages having interconnections in the high-density chip, a method based on the eddy current pulsed thermography (ECPT) is put forward to study the remaining life prediction of solder joints. A 3D induction heating finite element model is established, by which the crack length of defect solder joints can be distinguished using temperature field. At the same time, the remaining life of defect solder joints can be characterized by the length of the crack. Furthermore, the experiments are carried out on solder joints whose diameter is 0.4 mm. Both simulation and experiment results verify that it is reliable and convenient to use 3D induction heating based temperature field from ECPT to evaluate the remaining life of cracks in solder joints.
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In this paper, we summarize our recent experimental and theoretical works on observation and control of scroll wave (SW) turbulence. The experiments were conducted in a three-dimensional Belousov-Zhabotinsky reaction-diffusion system with chemical concentration gradients in one dimension. A spatially homogeneous external forcing was used in the experiments as a control; it was realized by illuminating white light on the light sensitive reaction medium. We observed that, in the oscillatory regime of the system, SW can appear automatically in the gradient system, which will be led to spatiotemporal chaos under certain conditions. A suitable periodic forcing may stabilize inherent turbulence of SW. The mechanism of the transition to SW turbulence is due to the phase twist of SW in the presence of chemical gradients, while modulating the phase twist with a proper periodic forcing can delay this transition. Using the FitzHugh-Nagumo model with an external periodic forcing, we confirmed the control mechanism with numerical simulation. Moreover, we also show in the simulation that adding temporal external noise to the system may have the same control effect. During this process, we observed a new state called "intermittent turbulence," which may undergo a transition into a new type of SW collapse when the noise intensity is further increased. The intermittent state and the collapse could be explained by a random process.
Assuntos
Física/métodos , Simulação por Computador , Difusão , Desenho de Equipamento , Concentração de Íons de Hidrogênio , Luz , Modelos Químicos , Modelos Teóricos , Dinâmica não Linear , OscilometriaRESUMO
Aiming to solve the defect detection problem of a small-size solder ball in the high density chip, heat conduction analysis based on eddy current pulsed thermography is put forward to differentiate various defects. With establishing the 3D finite element model about induction heating, defects such as cracks and void can be distinguished by temperature difference resulting from heat conduction. Furthermore, the experiment of 0.4 mm-diameter solder balls with different defects is carried out to prove that crack and void solder can be distinguished. Three kinds of crack length on a gull-wing pin are selected, including 0.24 mm, 1.2 mm, and 2.16 mm, to verify that the small defect can be discriminated. Both the simulation study and experiment result show that the heat conduction analysis method is reliable and convenient.
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The Na-ß-alumina battery (NBB) is one of the most promising energy storage technologies for integrating renewable energy resources into the grid. In the family of NBBs, Na-NiCl2 battery has been extensively studied during the past decade because it has a lower operating temperature, better safety, and good battery performance. One of the major issues with the Na-NiCl2 battery is material cost, which is primarily from Ni metal in the battery cathode. As an alternative, Zn is much cheaper than Ni, and replacing Ni with Zn in the cathode can significantly reduce the cost. In this work, we investigate the performance and reaction mechanism for a Na-ZnCl2 battery at 190 °C. Two-step reversible reactions are identified. During the first step of charging, NaCl reacts with Zn to produce a ribbon-type Na2ZnCl4 layer. This layer is formed at the NaCl-Zn interface rather than covering the surface of the Zn particles, which leads to an excellent cell rate capability. During the second step, the produced Na2ZnCl4 is gradually consumed to form ZnCl2 on the surface of Zn particles. The formed ZnCl2 covers most of the surface area of the Zn particles and shows a limited rate capability compared to that of the first step. We conclude that this limited performance of the second step is due to the passivation of Zn particles by ZnCl2, which blocks the electron pathway of the NaCl-Zn cathodes.
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Sodium-metal halide batteries have been considered as one of the more attractive technologies for stationary electrical energy storage, however, they are not used for broader applications despite their relatively well-known redox system. One of the roadblocks hindering market penetration is the high-operating temperature. Here we demonstrate that planar sodium-nickel chloride batteries can be operated at an intermediate temperature of 190 °C with ultra-high energy density. A specific energy density of 350 Wh kg(-1), higher than that of conventional tubular sodium-nickel chloride batteries (280 °C), is obtained for planar sodium-nickel chloride batteries operated at 190 °C over a long-term cell test (1,000 cycles), and it attributed to the slower particle growth of the cathode materials at the lower operating temperature. Results reported here demonstrate that planar sodium-nickel chloride batteries operated at an intermediate temperature could greatly benefit this traditional energy storage technology by improving battery energy density, cycle life and reducing material costs.
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A potassium-sulfur battery using K(+) -conducting beta-alumina as the electrolyte to separate a molten potassium metal anode and a sulfur cathode is presented. The results indicate that the battery can operate at as low as 150 °C with excellent performance. This study demonstrates a new type of high-performance metal-sulfur battery that is ideal for grid-scale energy-storage applications.
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Commercial sodium-sulphur or sodium-metal halide batteries typically need an operating temperature of 300-350 °C, and one of the reasons is poor wettability of liquid sodium on the surface of beta alumina. Here we report an alloying strategy that can markedly improve the wetting, which allows the batteries to be operated at much lower temperatures. Our combined experimental and computational studies suggest that addition of caesium to sodium can markedly enhance the wettability. Single cells with Na-Cs alloy anodes exhibit great improvement in cycling life over those with pure sodium anodes at 175 and 150 °C. The cells show good performance even at as low as 95 °C. These results demonstrate that sodium-beta alumina batteries can be operated at much lower temperatures with successfully solving the wetting issue. This work also suggests a strategy to use liquid metals in advanced batteries that can avoid the intrinsic safety issues associated with dendrite formation.
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Since the experimental observation of antiwaves in reaction-diffusion (RD) systems, the discrepancy between the theoretical prediction and the experimental observation on the transition from inwardly rotating chemical waves to normal waves remains an unsolved problem. Theoretical predictions using both RD model and complex Ginzberg-Landau equation indicate that there exists a trend in which wave vector approaches to zero in the transition process, while disordered plane waves near the onset were observed in experiment. This discrepancy motivated us to conduct a systematic research to investigate the transition. Using chlorite-iodide-malonic acid reaction as model system and with a thorough parameter scanning, we found clear trend that the wave vector decreased near the transition point, where wavelength diverged. This observation is consistent with the theoretical predictions. However, disordered plane waves appeared in the region near the onset. Comparing the experimental results with the results from numerical simulation, we found that spatial inhomogeneity of the diffusion coefficient was the main cause of the disordered plane waves.
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Difusão , Física/métodos , Algoritmos , Cloretos/química , Simulação por Computador , Iodetos/química , Malonatos/química , Modelos Teóricos , Dinâmica não Linear , Óleos/química , Água/químicaRESUMO
The effect of noise on chemical waves in a quasi-three-dimensional reaction-diffusion medium with a gradient in the third dimension is studied using the FitzHugh-Nagumo model [R. FitzHugh, Biophysics J. 1, 445 (1961)]. Numerical simulations reveal that noise of appropriate intensity can postpone the onset of turbulence and stabilize the three-dimensional (3D) waves which would otherwise undergo the gradient-induced collapse. It is also found that the 3D waves can be interrupted by incident irregularities when the noise is not too strong; it can be induced into complete turbulence when the noise is strong enough. A mathematical analysis is given based on the dependence of the oscillation frequency on the control parameter. It agrees qualitatively with our numerical findings.