RESUMO
In the title compound, C17H19NO3S2, the maximum deviation of atoms in the 2H-chromene ring system is 0.0097â (14)â Å and the piperidine ring adopts a chair conformation. The dihedral angle between the 2H-chromene ring and the piperidine ring (all atoms) is 87.59â (8)°. In the crystal, inversion dimers linked by pairs of C-Hâ¯O inter-actions generate R 2 (2)(22) loops. Further C-Hâ¯O hydrogen bonds link the dimers into [110] chains and weak aromatic π-π stacking [shortest centroid-centroid distance = 3.824â (8)â Å] is also observed.
RESUMO
In the title compound, C15H14ClNO2S2, the 2H-chromene ring system is essentially planar, with a maximum deviation of 0.0133â (10)â Å. Three C atoms and their attached H atoms of the pyrrolidine ring are disordered [occupany ratio 0.874â (7):0.126â (7)] with both disorder components adopting a twisted conformation. The dihedral angle between the 2H-chromene ring system and the major occupancy component of the pyrrolidine ring is 89.45â (7)°. In the crystal, inversion dimers linked by pairs of C-Hâ¯S and C-Hâ¯O inter-actions generate R (2) 2(24) and R (2) 2(10) loops, respectively. Further C-Hâ¯O hydrogen bonds link the dimers into [100] chains. C-Hâ¯π inter-actions also occur and there is very weak π-π stacking [inter-planar spacing = 3.650â (5)â Å; centroid-centroid distance = 4.095â (7)â Å] between inversion-related chloro-benzene rings.
RESUMO
There are two independent mol-ecules in the asymmetric unit of the title compound, C16H15NO3S2, in which the pyrrolidine rings adopt envelope conformations, with a methyl-ene C atom as the flap. The dihedral angles betweeen the near-planar 2H-chromene ring systems [maximum deviations = 0.0167â (20) and 0.0136â (19)â Å] and the pyrrolidine rings (all atoms) are 83.83â (11) and 82.43â (11)°. In the crystal, inversion dimers linked by pairs of C-Hâ¯O hydrogen bonds occur for one of the mol-ecules. Further C-Hâ¯O links involving both mol-ecules generate a three-dimensional network.
RESUMO
In the title compound, C13H12Cl N O2S2, the 2H-chromene ring system is almost planar, with a maximum deviation of 0.005â (2)â Å. The packing features C-Hâ¯S hydrogen bonds and π-π inter-actions between fused benzene rings of chromene [shortest centroid-centroid distances = 3.6553â (13) and 3.5551â (13)â Å].