Experimental investigation of the effect of topological insulator on the magnetization dynamics of ferromagnetic metal:BiSbTe1.5Se1.5andNi80Fe20heterostructure.

We have studied the spin-pumping phenomenon in ferromagnetic metal (FM) (Ni80Fe20)/topological insulator (TI) (BiSbTe1.5Se1.5) bilayer system to understand magnetization dynamics of FM in contact with a TI. TIs embody a spin-momentum-locked surface state that spans the bulk band gap. Due to this special spin texture of the topological surface state, the spin-charge interconversion efficiency of TI is even higher than that of heavy metals. We evaluated the parameters like effective damping coefficient (αeff), spin-mixing conductance (geff↑↓) and spin current density (jS0) to demonstrate an efficient spin transfer inNi80Fe20/BiSbTe1.5Se1.5heterostructure. To probe the effect of the topological surface state, a systematic low-temperature study is crucial as the surface state of TI dominates at lower temperatures. The exponential increase ofΔHfor all different thickness combinations of FM/TI bilayers and the enhancement of effective damping coefficient (αeff) with lowering temperature confirms that the spin chemical potential bias generated from spin-pumping induces spin current into the TI surface state. Furthermore, low-temperature measurements of effective magnetization (4πMeff) and magnetic anisotropy field (Hk) showed anomaly around the same temperature region where the resistivity of TI starts showing metallic behavior due to the dominance of conducting TI surface state. The anomaly inHkcan result from the emerging exchange coupling between the TI surface state and the local moments of the FM layer at the interface without any long-range ferromagnetic order in TI at the interface.

A short-circuited coplanar waveguide for low-temperature single-port ferromagnetic resonance spectroscopy setup to probe the magnetic properties of ferromagnetic thin films.

A coplanar waveguide shorted in one end is proposed, designed, and implemented successfully to measure the properties of magnetic thin films as a part of the vector network analyzer ferromagnetic resonance (FMR) spectroscopy setup. Its simple structure, potential applications, and easy installation inside the cryostat chamber made it advantageous especially for low-temperature measurements. It provides a wide band of frequencies in the gigahertz range essential for FMR measurements. Our spectroscopy setup with a short-circuited coplanar waveguide has been used to extract the Gilbert damping coefficient and effective magnetization values for standard ferromagnetic thin films, such as Permalloy (Py) and Cobalt (Co). The thickness and temperature-dependent studies of those magnetic parameters have also been done here for the afore-mentioned magnetic samples.

Photothermal Control of Helicity-Dependent Current in Epitaxial Sb2Te2Se Topological Insulator Thin-Films at Ambient Temperature.

Optical control of helicity-dependent photocurrent in topological insulator (TI) Sb2Te2Se has been studied at room temperature on epitaxial thin-films grown by pulsed laser deposition (PLD). Comparison with a theoretical model, which fits the data very well, reveals different contributions to the measured photocurrent. Study of the dependence of photocurrent on the angle of incidence (wave-vector) of the excitation light with respect to the sample normal helps to identify the origin of different components of the photocurrent. Enhancement and inversion of the photocurrent in the presence of the photothermal gradient for light incident on two opposite edges of the sample occur due to selective spin-state excitation with two opposite circularly polarized lights in the presence of the unique spin-momentum locked surface states. These observations render the PLD-grown epitaxial TI thin-films promising for optoelectronic devices such as sensors, switches, and actuators whose response can be controlled by polarization as well as the angle of incidence of light under ambient conditions. The polarization response can also be tuned by the photothermal effect by suitably positioning the incident light beam on the device.

Synthesis, characterisation and antioxidant activity of luteolin-vanadium(II) complex.

The complex formation between luteolin (L) and vanadium(IV) oxide sulphate monohydrate (VOSO4·H2O) was examined under UV-visible, infra-red spectroscopy, mass spectroscopy and NMR techniques. The spectroscopic data indicated that luteolin reacts with vanadium oxide cation (VO(+2)) through 4-carbonyl-5-hydroxy chelation site in the two luteolin molecule. The free radical antioxidant activity of the complex with respect to the parent molecule was evaluated using 1,1-diphenyl-2-picrylhydrazyl (DPPH), ferric reducing antioxidant power (FRAP) and 2,2'-azinobis 3-ethylbenzothiazoline-6-sulphonic acid diammonium salt (ABTS) methods. It was observed that the free radical scavenging activity and ferric ion reducing potential of luteolin was increased after the formation of complex with vanadium oxide (VO(+2)) cation.

Synthesis, Characterization, Antioxidant Status, and Toxicity Study of Vanadium-Rutin Complex in Balb/c Mice.

A new trend was developed for the formation of a complex between vanadium and flavonoid derivatives in order to increase the intestinal absorption and to reduce the toxicity of vanadium compounds. The vanadium-rutin complex was characterized by several spectroscopic techniques like ultraviolet (UV)-visible, Fourier transform infrared (FTIR), NMR, mass spectrometry, and microscopic evaluation by scanning electron microscopy. The mononuclear complex was formed by the interaction between vanadium and rutin with 1:2 metal to ligand stoichiometry. Antioxidant activity of the complex was evaluated by 1,1-diphenyl-2 picrylhydrazyl, ferric-reducing power, and 2,2'-azin-obis 3-ethylbenzothiazoline-6-sulphonic acid methods. It was shown that radical scavenging activity and ferric-reducing potential of free rutin was lower as compared with vanadium-rutin complex. The study was also investigated for oral acute toxicity and 28 days repeated oral subacute toxicity study of vanadium-rutin complex in balb/c mice. The vanadium-rutin complex showed mortality at a dose of 120 mg/kg in the balb/c mice. In 28 days repeated oral toxicity study, vanadium-rutin complex was administered to both sex of balb/c mice at dose levels of 90, 45, and 20 ppm, respectively. In addition, subacute toxicity study of vanadium-rutin complex (at 90 ppm dose level) showed increase levels of white blood cell (WBC), total bilirubin, alanine aminotransferase (ALT), alkaline phosphatase (ALP), aspartate aminotransferase (AST), creatinine, and blood urea nitrogen and decrease level of total protein (TP) as compared with control group. Histopathological study of vanadium-rutin showed structural alteration in the liver, kidney, and stomach at 90 ppm dose level. No observed toxic level of vanadium-rutin complex at 20 ppm dose level could be good for further study.