1.
Dalton Trans
; 50(45): 16514-16518, 2021 Nov 23.
Artigo
em Inglês
| MEDLINE
| ID: mdl-34761758
RESUMO
A mesoionic N-heterocyclic carbene-gold(I) complex with a unique Auâ¯H-C(methine) intramolecular hydrogen bonding interaction has been investigated in the solid state. The structure of this new neutral gold(I)-carbene was characterized by FT-IR and NMR spectroscopy, TGA, and X-ray diffraction techniques. Density functional theory (DFT) and atoms-in-molecule (AIM) analysis revealed that the gold-hydrogen bonding situation is more favored. Besides, the photophysical properties of the gold(I) complex were also investigated.