Light-modulated colour transformation in highly intertwined vertically growing silver tungstate tubes.

Achieving control over growth kinetics in chemical garden architectures is challenging due to the nonequilibrium conditions. In this study, we demonstrate the vertical growth of silver tungstate chemical garden tubes under both illuminated and dark conditions, a phenomenon not observed in a comparable silver-based system, specifically silver silicate, under light exposure. Physicochemical factors, viz. thermo chemical radius of the tungstate anion, its density-buoyancy relation, the osmotic pressure gradient, and the hydration enthalpy, contributed to the tube appearance in silver tungstate even in light. Tubes grown in light illumination were greyish black, while dark-grown tubes were creamy white, and both tubes appeared twisted and highly intertwined. The colour of the as obtained silver tungstate tubes could be transformed via exposure to light. In the presence of a strong oxidizing agent, the growing tubes retain the original creamy white colour even under illumination. Colour transformation in chemical garden tubes has not yet been observed, and this report could lead the way.

Dissimilar chemobrionic growth in copper silicate chemical gardens in the absence or presence of light.

The effect of the absence of light on chemical garden growth has been neglected although the gardens resemble hydrothermal vents that grow in dark in the sea/ocean. Herein, we report the differential growth of chemobrionic structures in copper silicate when identical reactions to yield copper silicate chemical gardens were carried out in the presence or absence of light. Irradiating the copper silicate chemical garden during its growth with different wavelengths of light independently resulted in morphologically divergent tubes.

Dark-induced vertical growth of chemobrionic architectures in silver-based precipitating chemical gardens.

The light sensitivity of many silver compounds has restricted the observation of silver-based chemical gardens. Here, we report for the first time, silver-based chemical gardens grown in the dark. An identical reaction kept in the light resulted in no such structures. We attribute the observation of silver-based chemobrionics to the avoidance of light.