Novel chitosan-zeolite X composite beads prepared by phase-inversion method for CO2 adsorptive capture.

The urgent need to mitigate carbon emissions from industrial heat production has led to the exploration of novel carbon-based materials for carbon capture. Chitosan, a versatile framework, has been widely utilized for embedding many materials such as grafted graphene oxide, zeolite, and activated carbon to enhance the carbon capture capacity of diverse carbon-based materials. Remarkably, the combination of chitosan and zeolite overcomes the inherent drawbacks of powdery zeolite, resulting in improved stability and efficiency in carbon capture applications. In this study, zeolite X-chitosan composite was successfully synthesized using phase inversion method followed by solvent exchange and air drying. The synthesis procedure described in this study presents a notable advantage in terms of simplicity and ease of fabrication. The combination of SEM and XRD analyses provided evidence that the composite exhibited a uniform arrangement of zeolite within the chitosan framework and maintained the original properties of the powdered zeolite. The adsorption capacity of the composite was first investigated by varying mass ratio of zeolite per chitosan. The composite with mass ratio that gave the best adsorption capacity were then tested under various temperatures (-20 °C, 0 °C, 30 °C, and 50 °C) and pressures (1 kPa, 3 kPa, 5 kPa, and 30 kPa). The application of different adsorption models was also employed to simulate the breakthrough curves. Furthermore, the material also underwent multiple continuous adsorption-desorption cycles showing its potential for repeated rechargeability. In contrast, the synthesis and characterization of copper ion-exchanged composite yielded significant drop in adsorption capacity, likely due to the formation of ligands or the inherent reactivity of Cu2+ ions towards hydroxide.

Granular-carbon supported nano noble-metal (Au, Pd, Au-Pd): new dual-functional adsorbent/catalysts for effective removal of toluene at low-temperature and humid condition.

Treatment of the volatile organic compounds (VOCs) especially aromatic compounds such as toluene at low temperature and in the highly humid condition is currently a great challenge. New dual functional adsorbent/catalysts have been developed in this study to minimize the mass-transfer limitation at low temperature. The ready-to-practically-use materials, which consisted nano-sized noble metal (Au, Pd, Au-Pd) supported on granular carbon (GC) have been prepared using a metal-sol method. The surface morphology, and structure of these granular materials were characterized to confirm the presence of nano-sized noble metal on the GC as well as the properties of the dual functional adsorbent/catalyst. The results of catalytic performance revealed that the presence of Pd played an important role in the formation of nano Au particles, which were the catalytic active-site for toluene oxidation. At 60% relative humidity and 150°C the dual functional adsorbent/catalyst, Au-Pd/GC, exhibited 97.2% toluene removal. Importantly, the kinetic analysis for the catalytic oxidation of nano-sized 0.5%Au-0.27%Pd/GC catalyst showed that the Langmuir-Hinshelwood mechanism provided a good fit towards the experimental data and allowed to determine the kinetic parameters of the reaction-rate law -rA=k⋅KA⋅CA1+KA⋅CA⋅KO2⋅CO21+KO2.CO2. The activation energy, adsorption enthalpy of toluene, and oxygen on the catalyst were reported.