1.
Chem Commun (Camb)
; 51(5): 911-3, 2015 Jan 18.
Artigo
em Inglês
| MEDLINE
| ID: mdl-25434868
RESUMO
Cyclometallation of 2-(1-naphthyl)-pyridine is described. While cyclopalladation results in a five-membered metallacycle, cycloauration displays a completely orthogonal regioselectivity, resulting in the six-membered ring analogue. Bromination of the gold metallacycle results in the new C-H functionalisation product 2-(8-bromonaphth-1-yl)pyridine.