A bioinspired approach for shaping Au nanostructures: the role of biomolecule structures in shape evolution.

A new approach for shaping Au nanostructures by tuning the molecular structure of biomolecules has been explored. Different molecules, such as catechol, rutin, and quercetin, which have structural similarity to the catechol ring, were used to induce Au nanostructures under similar conditions. The as-synthesized nanostructures are characterized by using TEM, XPS, XRD, and UV/Vis spectral measurements. The growth mechanism for the formation of these noble metal shapes and the role of the molecular structure of the stabilizing/reducing agent were investigated by using TEM and UV/Vis spectral measurements. The structure and functional groups of the reducing/stabilizing agent play a vital role in the shape evolution of nanostructures. The electrocatalytic activity of different nanostructures in the reduction of oxygen was investigated and was found to be shape-dependent.

A facile approach for in situ synthesis of graphene-branched-Pt hybrid nanostructures with excellent electrochemical performance.

A facile and green approach for the synthesis of highly electroactive branched Pt nanostructures well dispersed on graphene has been developed by in situ reduction of graphene oxides and Pt(iv) ions in an aqueous medium. The as-synthesized branched Pt and graphene hybrid nanomaterials (GR-BPtNs) were thoroughly characterized using Transmission Electron Microscope (TEM), UV-Visible spectroscopy, Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA) and Raman spectroscopy. This report clearly exploits the decisive role of the graphene support, the pH of the solution and the stabiliser on shaping the branched morphology of the Pt nanostructures well dispersed on graphene. Cyclic voltammetry, chronoamperometry and electrochemical impedance spectroscopy (EIS) measurements were employed to investigate the electrocatalytic performance and durability of GR-BPtNs towards methanol oxidation and oxygen reduction. The results reveal that the synergetic effect of the graphene support and the branched morphology triggers electrocatalytic performance and robust tolerance to surface poisoning of GR-BPtNs.

A facile approach for morphosynthesis of Pd nanoelectrocatalysts.

A facile approach has been developed for synthesis of highly-structured, anisotropic Pd nanostructures. The dendritic Pd nanostructures show superior performance toward oxidation of formic acid and methanol for fuel cell application.