RESUMO
The increasing application of membrane filtration in water and wastewater treatment necessitates techniques to improve performance, especially in fouling control. Ultrasound is one promising technology for this purpose as cavitational effects facilitate continuous cleaning of the membrane. This research studied the ultrafiltration of lake water in systems with constant permeate flux under medium frequency (45â kHz) ultrasound irradiation. Fouling was investigated by monitoring transmembrane pressure (TMP) using continuous or intermittent ultrasound irradiation and dead-end or crossflow operation. Best performance was observed with continuous ultrasound irradiation in crossflow mode. Intermittent irradiation reduced the rate of TMP build-up but nevertheless allowed irreversible fouling to develop.
Assuntos
Incrustação Biológica/prevenção & controle , Ultrafiltração , Ultrassom , Purificação da Água , Membranas ArtificiaisRESUMO
The low-level presence of emerging contaminants (ECs) in the environment has raised a great concern due to their persistence, chronic toxicological, and endocrine disrupting effects on terrestrial and aquatic organisms. Wastewater treatment plants (WWTPs) have become hotspots for the spread of these contaminants to the environment as conventional processes are not efficient in removing them. Thus, the integration of advanced treatment methods within the chain of WWTPs is very essential. In this study, the innovative hybrid process USAMe® which integrates ultrasound irradiation (US), adsorption (A) and membrane filtration (Me) was investigated for the removal of ECs from secondary effluents. Diclofenac, carbamazepine, and amoxicillin were selected due to their large consumption and frequent presence in the aquatic environment. All three ECs were spiked into real secondary wastewater effluent at two concentrations of 10 ppm and 100 ppb. Membrane ultrafiltration and its combination with US (USMe) or adsorption (AMe) were also studied as control tests. The hybrid combination of all the three methods in the USAMe® processes elevated the EC removals to above 99% as compared to only around 90% in the AMe process. All effluents of the hybrid USAMe® processes gave "No Effect" to D. magna, with immobilization of ≤20%. Therefore, results showed that the USAMe® process was efficient in not only removing ECs, but also in generating safe and less toxic treated effluents; thereby displaying its potential as an advanced method for wastewater treatment.
Assuntos
Membranas Artificiais , Núcleo Familiar , Ultrafiltração/métodos , Águas Residuárias/química , Poluentes Químicos da Água/isolamento & purificação , Adsorção , Poluentes Químicos da Água/químicaRESUMO
Advanced wastewater treatment is necessary to effectively remove emerging contaminants (ECs) with chronic toxicity, endocrine disrupting effects, and the capability to induce the proliferation of highly resistant microbial strains in the environment from before wastewater disposal or reuse. This paper investigates the efficiency of a novel hybrid process that applies membrane ultrafiltration, activated carbon adsorption, and ultrasound irradiation simultaneously to remove ECs. Diclofenac, carbamazepine, and amoxicillin are chosen for this investigation because of their assessed significant environmental risks. Removal mechanisms and enhancement effects are analysed in single and combined processes. The influence of adsorbent dose and ultrasonic frequency to EC removal are also investigated. Results suggest that adsorption is probably the main removal mechanism and is affected by the nature of ECs and the presence of other components in the mixture. Almost complete removals are achieved in the hybrid process for all ECs.